Thermal and Physical Characterization of PEG Phase Change Materials Enhanced by Carbon-Based Nanoparticles.

This paper presents the preparation and thermal/physical characterization of phase change materials (PCMs) based on poly(ethylene glycol) 400 g·mol and nano-enhanced by either carbon black (CB), a raw graphite/diamond nanomixture (G/D-r), a purified graphite/diamond nanomixture (G/D-p) or nano-Diamond nanopowders with purity grades of 87% or 97% (nD87 and nD97, respectively). Differential scanning calorimetry and oscillatory rheology experiments were used to provide an insight into the thermal and mechanical changes taking place during solid-liquid phase transitions of the carbon-based suspensions. PEG400-based samples loaded with 1.

Activity-modulated phase transition in a two-dimensional mixture of active and passive colloids.

We study a two-dimensional binary mixture of active and passive colloids as an idealized model of an hybrid aggregate of living cells and inert particles. We perform molecular dynamics simulations of this system using two different thermostats, and we systematically investigate the effect of varying these two effective temperatures on the system behavior, as characterized by its density, structure and thermoelastic properties. Our results indicate that the presence of active colloids shifts the mixture towards the liquid state and renders it more deformable.

NePCM Based on Silver Dispersions in Poly(Ethylene Glycol) as a Stable Solution for Thermal Storage.

The main objective of this study is to design and characterize silver suspensions based on poly(ethylene glycol) PEG400, Ag/PEG400, as energy storage media for low-temperature applications. A polyvinylpyrrolidone (PVP) treatment was applied to ~22 nm silver nanoparticles to ensure good stability in poly(ethylene glycol). An array of different experimental techniques was utilized to analyze the molecular mass and purity of base poly(ethylene glycol), morphology of dry PVP-capped Ag nanoparticles, hydrodynamic average size of dispersed Ag particles, as well as thermal stability of PEG400 and Ag/PEG400 dispersions.