Sustainable lindane waste remediation: Surfactant-driven residual DNAPL extraction and oxidation in a real landfill (LIFE SURFING).

The LIFE SURFING Project was carried out at the Bailin Landfill in Sabiñánigo, Spain (2020-2022), applying Surfactant Enhanced Aquifer Remediation (SEAR) and In Situ Chemical Oxidation (S-ISCO) in a 60-meter test cell beneath the old landfill, to remediate a contaminated aquifer with dense non-aqueous phase liquid (DNAPL) from nearby lindane production. The project overcame traditional extraction limitations, successfully preventing groundwater pollution from reaching the river. In spring 2022, two SEAR interventions involved the injection of 9.

Remediation of groundwater polluted with lindane production wastes by conductive-diamond electrochemical oxidation.

This work studies the remediation of groundwater saturated with dense non-aqueous phase liquid (DNAPL) from lindane production wastes by electrochemical oxidation. DNAPL-saturated groundwater contains up to 26 chlorinated organic compounds (COCs), including different isomers of hexachlorocyclohexane (HCH). To do this, polluted groundwater was electrolysed using boron-doped diamond (BDD) and stainless steel (SS) as anode and cathode, respectively, and the influence of the current density on COCs removal was evaluated in the range from 5 to 50 mA cm.

Solar-assisted oxidation of organochlorine pesticides in groundwater using persulfate and ferrioxalate.

The oxidation of hexachlorocyclohexane isomers in the aqueous phase (Milli-Q and groundwater) was studied using persulfate activated by ferrioxalate and solar light at circumneutral pH. The experiments were conducted in a solar simulator reactor with local radiation fluxes q= 1.12·10 E cms and in compound parabolic collectors with solar light (q≈10 E cms) for 390 min.

Disinfection of polymicrobial urines by electrochemical oxidation: Removal of antibiotic-resistant bacteria and genes.

In this work, data obtained from the University Hospital Complex of Albacete (Spain) were selected as a case study to carry out the disinfection experiments. To do this, different configurations of electrochemical reactors were tested for the disinfection of complex urines. Results showed that 4-6 logs bacterial removal were achieved for every bacterium tested when working with a microfluidic flow-through reactor after 180 min (0.

Electrochemical Technologies to Decrease the Chemical Risk of Hospital Wastewater and Urine.

The inefficiency of conventional biological processes to remove pharmaceutical compounds (PhCs) in wastewater is leading to their accumulation in aquatic environments. These compounds are characterized by high toxicity, high antibiotic activity and low biodegradability, and their presence is causing serious environmental risks. Because much of the PhCs consumed by humans are excreted in the urine, hospital effluents have been considered one of the main routes of entry of PhCs into the environment.

A review on disinfection technologies for controlling the antibiotic resistance spread.

The occurrence of antibiotic-resistant bacteria (ARB) in water bodies poses a sanitary and environmental risk. These ARB and other mobile genetic elements can be easily spread from hospital facilities, the point in which, for sure, they are more concentrated. For this reason, novel clean and efficient technologies are being developed for allowing to remove these ARB and other mobile genetic elements before their uncontrolled spread.

A tube-in-tube membrane microreactor for tertiary treatment of urban wastewaters by photo-Fenton at neutral pH: A proof of concept.

This work presents a disruptive approach to promote highly-efficient photo-Fenton process at neutral pH under continuous mode operation. The system consists of a tube-in-tube membrane reactor designed for continuous-flow titration of low iron doses to the annular reaction zone (ARZ). A concentrated acidic ferrous ion (Fe) solution is fed by the lumen-side of the membrane, permeating through the membrane pores (inside-out mode), being dosed and uniformly delivered to the membrane shell-side.

Enhancement of UV disinfection of urine matrixes by electrochemical oxidation.

This work focuses on the removal of antibiotic-resistant bacteria (ARB) contained in hospital urines by UV disinfection enhanced by electrochemical oxidation to overcome the limitations of both single processes in the disinfection of this type of effluents. UV disinfection, electrolysis, and photoelectrolysis of synthetic hospital urine intensified with K. pneumoniae were studied.

Improving the biodegradability of hospital urines polluted with chloramphenicol by the application of electrochemical oxidation.

This work focuses on improving the biodegradability of hospital urines polluted with antibiotics by electrochemical advanced oxidation processes (EAOPs). To do this, chloramphenicol (CAP) has been used as a model compound and the influence of anodic material (Boron Doped Diamond (BDD) and Mixed Metal Oxide (MMO)) and current density (1.25-5 mA cm) on the toxicity and the biodegradability was evaluated.

Degradation of dye Procion Red MX-5B by electrolytic and electro-irradiated technologies using diamond electrodes.

This work focuses on the treatment of synthetic wastewater polluted with dye Procion Red MX-5B by different Electrochemical Advanced Oxidation Processes (EAOP) based on diamond anodes. The influence of the current density and the supporting electrolyte has been studied on dye removal and total mineralization of the organic matter. Results show that electrolysis with diamond electrodes is a suitable technology for an efficient degradation of dye.

Electrolysis with diamond anodes: Eventually, there are refractory species!

In this work, synthetic wastewater polluted with ionic liquid 1-butyl-3-methylimidazolium (Bmim) bis(trifluoromethanesulfonyl)imide (NTf) undergoes four electrolytic treatments with diamond anodes (bare electrolysis, electrolysis enhanced with peroxosulfate promoters, irradiated with UV light and with US) and results obtained were compared with those obtained with the application of Catalytic Wet Peroxide Oxidation (CWPO). Despite its complex heterocyclic structure, Bmim cation is successfully depleted with the five technologies tested, being transformed into intermediates that eventually can be mineralized. Photoelectrolysis attained the lowest concentration of intermediates, while CWPO is the technology less efficient in their degradation.

Sono- and photoelectrocatalytic processes for the removal of ionic liquids based on the 1-butyl-3-methylimidazolium cation.

In this work, sono- and photoelectrolysis of synthetic wastewaters polluted with the ionic liquids 1-Butyl-3-methylimidazolium acetate (BmimAc) and chloride (BmimCl) were investigated with diamond anodes. The results were compared to those attained by enhancing bare electrolysis with irradiation by UV light or with the application of high-frequency ultrasound (US). Despite its complex heterocyclic structure, the Bmim cation was successfully depleted with the three technologies that were tested and was mainly transformed into four different organic intermediates, an inorganic nitrogen species and carbon dioxide.

Electrolytic and electro-irradiated technologies for the removal of chloramphenicol in synthetic urine with diamond anodes.

Hospital effluents are a major source for the occurrence of pharmaceuticals in the environment. In this work, the treatment of synthetic urine polluted with chloramphenicol is studied by using three different conductive-diamond electrochemical oxidation technologies: electrolysis (single electrolysis), photoelectrolysis and high-frequency ultrasound sonoelectrolysis. These technologies were evaluated at 10 and 100 mA cm.

Synergistic integration of sonochemical and electrochemical disinfection with DSA anodes.

This work focuses on the disinfection actual urban wastewater by the combination of ultrasound (US) irradiation and electrodisinfection with Dimensionally Stable Anodes (DSA). First, the inactivation of Escherichia coli (E. coli) during the sonochemical disinfection was studied at increasing ultrasound power.

Scale-up of electrolytic and photoelectrolytic processes for water reclaiming: a preliminary study.

This work focuses on the scale-up of electrochemical and photoelectrochemical oxidation processes with diamond anodes for the removal of organic pollutants and disinfection of treated urban wastewater, two of the most important parameters for the reclaiming of wastewater. The removal of organics was studied with actual biologically treated urban wastewater intensified with 100 mg dm(-3) of caffeine, added as a trace organic pollutant. The disinfection was also studied with biologically treated urban wastewater, and Escherichia coli was used to monitor the efficiency of the process.

Electrolytic and electro-irradiated processes with diamond anodes for the oxidation of persistent pollutants and disinfection of urban treated wastewater.

This paper analyzes the advantages and drawbacks of the combination of UV irradiation with electrolysis with the aim to give insight about the feasibility of the application of this technology for the reclaiming of conventionally-treated wastewater. The oxidation of synthetic solutions containing five selected model complex pollutants has been compared, showing that UV irradiation improves the results of electrolysis for progesterone, metoprolol and caffeine and deteriorates the performance for the degradation of sulfamethoxazole and dimethyl-phthalate. Differences observed becomes lower when mineralization is compared showing that the effects of UV irradiation are diluted when a mixture of species is oxidized.

Conductive diamond sono-electrochemical disinfection (CDSED) for municipal wastewater reclamation.

In the present work, the disinfection of actual effluents from a municipal wastewater treatment plant (WWTP) by a conductive diamond sono-electrochemical process was assessed. First, efficiency of single electrodisinfection process with diamond anodes (without the contribution of ultrasounds) was studied, finding that the total disinfection can be attained at current charges applied below 0.02kAhm(-3).

Effect of bipolar electrode material on the reclamation of urban wastewater by an integrated electrodisinfection/electrocoagulation process.

This work presents an integrated electrodisinfection/electrocoagulation (ED-EC) process for urban wastewater reuse that employs iron bipolar electrodes. Boron doped diamond (BDD) was used as the anode and stainless steel (SS) as the cathode. A perforated iron plate was introduced between the anode and cathode to function as a bipolar electrode.

Optimization of an integrated electrodisinfection/electrocoagulation process with Al bipolar electrodes for urban wastewater reclamation.

In this work, a novel integrated electrochemical process for urban wastewater regeneration is described. The electrochemical cell consists in a Boron Doped Diamond (BDD) or a Dimensionally Stable Anode (DSA) as anode, a Stainless Steel (SS) as cathode and a perforated aluminum plate, which behaves as bipolar electrode, between anode and cathode. Thus, in this cell, it is possible to carry out, at the same time, two different electrochemical processes: electrodisinfection (ED) and electrocoagulation (EC).