Optimization and in-house validation of the TDA-AAS method for mercury control in water and wastewater treatment plant sludges.

The thermal decomposition, amalgamation, and atomic absorption spectrometry (TDA-AAS) method was validated for mercury (Hg) determination in sludge samples. A linear range was obtained from 30 to 200 ng. The TDA-AAS method provides a limit of quantification (LOQ) well below the legal maximum admitted concentration of Hg in sludge samples, which makes it suitable to measure its concentrations at the imposed legal limits, and for monitoring studies of Hg trace levels in sludge samples.