Considering the potential eutrophication risk of phosphonate and scarcity of phosphorus resources, the oxidation of organically-bound phosphorus to orthophosphate (ortho-P) is an important prerequisite for high-value phosphorus recovery. This study investigated efficiency and mechanism of different categories of phosphonates oxidation to ortho-P by classical Fenton and practical electrochlorination Fenton-like processes. The target phosphonates included two categories: nitrogen-free phosphonates (NF-PPs), i.
View Article and Find Full Text PDFNowadays, water splitting has been recognized as one of the most attractive ways to produce clean hydrogen energy. Herein, a novel sulfur-doped layered double-hydroxide (namely, S-NiCo-LDH) electrocatalyst with nanocage structure is prepared. After the etching treatment with Ni ions, the spatial structure of the catalysts is opened, and the hydrophilicity is improved, which will enhance the adsorption capacity for HO to provide convenience for hydrogen evolution reaction (HER).
View Article and Find Full Text PDFHeavy metal complexes from the industrial wastewater induce risks for the humans and ecosystems, yet are valuable metal resources. For energy saving and emission reduction goals, the simultaneous decomplexation and recovery of metal resources is the ideal disposal of wastewater with heavy metal complexes. Herein, a self-catalytic decomplexation scheme is developed via an electrochemical ozone production (EOP) system to achieve efficient decomplexation and Cu recovery.
View Article and Find Full Text PDFPhosphonate used as scale inhibitor is a non-negligible eutrophic contaminant in corresponding polluted waters. Besides, its conversion to orthophosphate (ortho-P) is a precondition for realizing bioavailable phosphorus recovery. Due to the feeble degradation efficiency with less than 30 % from classical Fenton commonly used in industrial wastewater treatment and itself vulnerable to strong inhibition interference of matrix chloride ions, we proposed an electrochemical approach to transform the native salt in the solution into oxidizing substances, sort of achieving beneficial utilization of matrix waste, and enhanced the ortho-P conversion rate of 1-Hydroxyethane-1,1-diphosphonic acid (HEDP) to 89.
View Article and Find Full Text PDFThe cultivated peanut ( L.) is a significant oil and cash crop globally. Hundred-pod and -seed weight are important components for peanut yield.
View Article and Find Full Text PDFHow to efficiently treat municipal solid waste (MSW) has become one of the critical solutions in response to the call for "carbon neutrality". Here, the waste polypropylene nonwoven fabric of waste diapers was converted into hierarchical nanoporous biochar (HPBC) through pre-carbonization and activation processes as an ideal precursor for supercapacitors (SCs) with excellent performance. The prepared HPBC-750-4 with an ultrahigh specific surface area (3838.
View Article and Find Full Text PDFBackground: Osteoporosis is a common systemic bone disease that leads to bone fragility and increases the risk of fracture. However, the pathogenesis of osteoporosis is considered to be highly complex. The exosomes can regulate the communication between cells.
View Article and Find Full Text PDFBackground: As a typical high-disability neurodegenerative disease, Parkinson's disease (PD) progresses variably, and patients who are clinically insensitive to dopaminergic therapy and whose symptoms fail to improve are commonly observed. As a result, achieving early neuron protection is critical.
Methods/design: The NET-PD study is a 2-year prospective single-center, double-blind, multi-arm, delayed-start, sham-controlled clinical trial assessing the long-term neuroprotective effect of intermittent theta burst stimulation (iTBS) in PD patients.
Chloroacetonitriles (CANs) are highly toxic nitrogenous disinfection by-products (N-DBPs), which frequently appear in water supply systems and have attracted widespread attention. UV/persulfate (PS) is an effective method to degrade CANs. Bromide (Br) is widespread in aquatic environments and reacts with oxidative radicals to produce secondary reactive bromine species (RBS), which affects the degradation of CANs by UV/PS.
View Article and Find Full Text PDFThe land ice contribution to global mean sea level rise has not yet been predicted using ice sheet and glacier models for the latest set of socio-economic scenarios, nor using coordinated exploration of uncertainties arising from the various computer models involved. Two recent international projects generated a large suite of projections using multiple models, but primarily used previous-generation scenarios and climate models, and could not fully explore known uncertainties. Here we estimate probability distributions for these projections under the new scenarios using statistical emulation of the ice sheet and glacier models.
View Article and Find Full Text PDFAlthough the influence of environmental factors on the microbial community in water sources is crucial, it is seldom evaluated. The seasonal relationship between microbial diversity of bacteria and fungi and environmental factors was investigated in a large drinking-water reservoir using Illumina MiSeq sequencing. Forty-one bacterial phyla and nine fungal phyla were analyzed in the Qingcaosha Reservoir, Shanghai, China.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
October 2020
Pine Island Glacier and Thwaites Glacier in the Amundsen Sea Embayment are among the fastest changing outlet glaciers in West Antarctica with large consequences for global sea level. Yet, assessing how much and how fast both glaciers will weaken if these changes continue remains a major uncertainty as many of the processes that control their ice shelf weakening and grounding line retreat are not well understood. Here, we combine multisource satellite imagery with modeling to uncover the rapid development of damage areas in the shear zones of Pine Island and Thwaites ice shelves.
View Article and Find Full Text PDFThe release of contaminants of emerging concern (CECs) into water bodies has aroused wide concern in recent years. Little information on the characteristics of CECs to pose potential risks even at low concentrations in urban water systems of Shanghai is available. This study investigated the occurrence and spatial distribution in source water, as well as the fates by drinking water treatment processes for organic compounds including 35 pesticides, 17 antibiotics, 7 microcystins (MCs), and 10 disinfection by-products (DBPs).
View Article and Find Full Text PDFEarlier large-scale Greenland ice sheet sea-level projections (e.g., those run during the ice2sea and SeaRISE initiatives) have shown that ice sheet initial conditions have a large effect on the projections and give rise to important uncertainties.
View Article and Find Full Text PDFThe long-term low concentrations of trace "contaminants of emerging concern" (CECs) can have potential toxic effects on human health and serious risks to the ecological environment. This study investigated the occurrence, spatial distributions, and seasonal variations of 65 target CECs, including 35 pesticides, 17 antibiotics, 7 microcystins, 5 estrogens, and 1 plasticizers in Shanghai's source water. The detected pesticides and antibiotics of sulfonamides and macrolides were relatively ubiquitous in source water of Shanghai, with levels decreasing in the following order: pesticides (average (avg.
View Article and Find Full Text PDFMaterials (Basel)
February 2018
Cr adsorption on wood-based powdered activated carbon (WPAC) was characterized by scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The highest Cr(VI) adsorption (40.04%) was obtained under acidic conditions (pH 3), whereas Cr removal at pH 10 was only 0.
View Article and Find Full Text PDFMolecular weight (MW) distributions in source and treated water in Shanghai, China were investigated to understand the relationship between trihalomethanes formation potential/N-nitrosodimethylamine formation potential (THMFP/NDMAFP) and dissolved organic carbon (DOC) for different MW ranges (<1K, 1-10K, 10-30K, >30KDa). The result of MW distributions in source water indicated a relationship between THMFP/NDMAFP and DOC such that DOC for <1K and 1-30KDa DOC were linearly related to THMFP and NDMAFP, respectively. In treated water, >30KDa THMFP was totally removed whereas <1KDa THMFP showed linear relationships with R=0.
View Article and Find Full Text PDFZhongguo Zhong Yao Za Zhi
March 2015
Objective: To study the effect of single administration of aqueous extracts from aconite on "dose-toxicity" relationship and "time-toxicity" relationship of mice hearts, through changes in electrocardiogram (ECG) and serum biochemical indexes.
Method: Mice were grouped according to different drug doses and time points, and orally administered with water extracts from aconite for once to observe the changes of mice ECG before and after the administration, calculate visceral indexes heart, liver and kidney, and detect levels of CK, LDH, BNP and CTn-I in serum.
Result: According to the "time-toxicity" relationship study, at 5 min after oral administration with aqueous extracts from aconite in mice, the heart rate of mice began rising, reached peak at 60 min and then slowly reduced; QRS, R amplitude, T duration and amplitude and QT interval declined at 5 min, reduced to the bottom at 60 min and then gradually elevated.
Phys Chem Chem Phys
February 2015
Magnetic iron oxide/graphene oxide (MGO) with high iron loading (51 wt%) has been successfully synthesized using the co-precipitation method, and then used as adsorbents for the removal of arsenate and arsenite from aqueous solutions. The resulting MGO possesses desirable magnetic properties (12.8 emu g(-1)) and excellent adsorption properties for the removal of As(III) and As(IV) with significantly enhanced adsorption capacities of 54.
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