To meet the rising requirement of photovoltaic compounds for modernized hi-tech purpose, we designed six new molecules (DTPD1-DTPD6) from banana shaped small fullerene free chromophore (DTPR) by structural tailoring at terminal acceptors. Frontier molecular orbitals (FMOs), density of states (DOS), open circuit voltage (V), transition density matrix (TDM) analysis, optical properties, reorganization energy value of hole and electron were determined utilizing density function theory (DFT) and time-dependent density function theory (TD-DFT) approaches, to analyze photovoltaic properties of said compounds. Band gap contraction (āEā=ā2.
View Article and Find Full Text PDFUsing interview and observational data from a busy and research-intensive breast cancer service in the United Kingdom, we discuss recent developments in personalised medicine. Specifically, we show how clinical and research practices meet in clinical pathways that are reconfigured in response to changing approaches of diagnosing, monitoring, treating and understanding cancers. Clinical pathways are increasingly sensitive to changes in evidence deduced through new technologies and therapies as well as decisions based on intensive, iterative analysis of data collected across a range of platforms.
View Article and Find Full Text PDFBreast cancer is one of the leading causes of death among women, more so than all other cancers. The accurate diagnosis of breast cancer is very difficult due to the complexity of the disease, changing treatment procedures and different patient population samples. Diagnostic techniques with better performance are very important for personalized care and treatment and to reduce and control the recurrence of cancer.
View Article and Find Full Text PDFBreast cancer is the most common cause of death for women worldwide. Thus, the ability of artificial intelligence systems to detect possible breast cancer is very important. In this paper, an ensemble classification mechanism is proposed based on a majority voting mechanism.
View Article and Find Full Text PDFHuman action recognition (HAR) has emerged as a core research domain for video understanding and analysis, thus attracting many researchers. Although significant results have been achieved in simple scenarios, HAR is still a challenging task due to issues associated with view independence, occlusion and inter-class variation observed in realistic scenarios. In previous research efforts, the classical bag of visual words approach along with its variations has been widely used.
View Article and Find Full Text PDFUncontrolled arterial bleeding during laparoscopic cholecystectomy is a serious problem and may increase the risk of bile duct damage. Therefore, accurate identification of the anatomy of the cystic artery is very important. Cystic artery is notoriously known to have a highly variable branching pattern.
View Article and Find Full Text PDFSurg Laparosc Endosc Percutan Tech
February 2013
This was a prospective randomized controlled study designed to compare laparoscopic and open interval appendectomy and involved 100 patients of appendicular phlegmon. After initial conservative management, patients were divided into 2 groups of 50 each and interval appendectomy was performed by laparoscopy in one of the groups and by open method in the other. Mean operative time in open surgery was 33.
View Article and Find Full Text PDFEpiploic appendagitis is a rare cause of acute abdomen. Depending on the site of occurrence, it can mimic any cause of acute abdomen or disease of the colon and caecal appendix; making its preoperative diagnosis very difficult. We present here a case of a 7-year-old boy misdiagnosed preoperatively as acute appendicitis and later on, upon surgical exploration, found to have caecal appendagitis.
View Article and Find Full Text PDF