Nanoparticles of zinc ferrite (ZnFeO) and copper ferrite (CuFeO) were synthesized, and characterized, and these materials were applied for removal of organic dyes of alizarin yellow R (AYR), thiazole yellow G (TYG), Congo red (CR), and methyl orange (MO) from industrial wastewater through adsorption technique. Synthesis of ZnFeO and CuFeO was achieved through chemical co-precipitation method. These nanomaterials were characterized for physicochemical properties using XRD, FTIR, BET, VSM, DLS, Zeta-potential, and FESEM-EDX analytical instruments.
View Article and Find Full Text PDFThis study presents the results of synthesis and characterization of nanoparticles of cobalt ferrite (CoFeO) and nickel ferrite (NiFeO) using co-precipitation method followed by application for removal of hazardous organic textile dyes of thiazole yellow G (TYG) and alizarin yellow R (AYR). XRD analysis confirmed formation of cubic spinel structure with average crystallite sizes at 16.07 nm and 13.
View Article and Find Full Text PDFTo investigate the seasonal and spatial variations of ion chemistry of fine particles in Northern Zhejiang Province (NZP), China, one year-long field sampling was conducted at four representative sites (two urban, one suburb, and one rural sites) in both cities of Hangzhou and Ningbo from December 2014 to November 2015. Twelve water soluble inorganic ions (WSII) were characterized in this comprehensive study. The annual average of PM concentration in NZP as overall was 66.
View Article and Find Full Text PDFAn intensive measurement campaign was undertaken to characterize eight fractions of organic carbon (OC) and elemental carbon (EC) in particulate matter (PM) at four urban sites with different pollution characteristics during summer, post-monsoon, and winter at Kanpur, India. Speciation samplers were used to collect particulate samples on quartz filters followed by analysis of OC and EC using Interagency Monitoring of Protected Visual Environments (IMPROVE)-based thermal/optical reflectance (TOR) method. Based on 24-h average results at each site, the highest levels of OC and EC were observed during winter as 96.
View Article and Find Full Text PDFThe characterization of aerosol acidity has received increased attention in recent years due to its influence on atmospheric visibility, climate change and human health. Distribution of water soluble inorganic (WSI) ions in 12 different size fractions of aerosols was investigated under two different atmospheric conditions (smoke-haze and non-haze periods) in 2012 using the Micro-Orifice Uniform Deposit Impactor (MOUDI) and nano-MOUDI for the first time in Singapore. To estimate the in situ acidity ([H(+)]Ins) and in situ aerosol pH (pHIS), the Aerosol Inorganic Model version-IV under deliquescent mode of airborne particles was used at prevailing ambient temperature and relative humidity.
View Article and Find Full Text PDFAn optimized protocol for induction and establishment of Agrobacterium rhizogenes-mediated hairy root cultures of Plumbago zeylanica L. was developed through selection of suitable explant type and the bacterial strain. The infection of internodal explants from an in vivo plant and leaves of in vitro origin with the A4 strain resulted in the emergence of hairy roots at a transformation frequency of 86.
View Article and Find Full Text PDFToxic elements present in airborne particulate matter (PM) are associated with human health effects; however, their toxic characteristics depend on the source of their origins and their concentrations in ambient air. Twenty four elements (Al, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Mg, Mn, Na, Ni, Pb, Se, Sr, Te, Tl, and Zn) in 12 different size fractions of PM ranging from 10 nm to 10 μm were characterized in Singapore during two different atmospheric conditions (smoke haze and non-haze periods) in 2012 for the first time. In addition, their possible sources were identified based on backward air trajectory analysis and principal component analysis (PCA).
View Article and Find Full Text PDFRecurring biomass burning-induced smoke haze is a serious regional air pollution problem in Southeast Asia (SEA). The June 2013 haze episode was one of the worst air pollution events in SEA. Size segregated particulate samples (2.
View Article and Find Full Text PDFToxic particulate elements present in cigarette smoke pose health threats to the life of smokers due to direct inhalation and at the same time increase health risks to non-smokers present in the vicinity of smokers because of their exposure. This study conducted a series of experiments using a controlled experimental chamber, equipped with simulated smoking conditions for characterization of particulate trace elements in mainstream and sidestream cigarette smoke. Four popular commercial cigarette brands available in Singapore market were used in this study.
View Article and Find Full Text PDFGaseous ammonia (NH3) is the most abundant alkaline gas in the atmosphere. In addition, it is a major component of total reactive nitrogen. The largest source of NH3 emissions is agriculture, including animal husbandry and NH3-based fertilizer applications.
View Article and Find Full Text PDFArch Environ Occup Health
July 2013
This paper examines the effect of outdoor air pollution on respiratory disease in Kanpur, India, based on data from 2006. Exposure to air pollution is represented by annual emissions of sulfur dioxide (SO(2)), particulate matter (PM), and nitrogen oxides (NO(x)) from 11 source categories, established as a geographic information system (GIS)-based emission inventory in 2 km × 2 km grid. Respiratory disease is represented by number of patients who visited specialist pulmonary hospital with symptoms of respiratory disease.
View Article and Find Full Text PDFAerosol acidity is one of the most important parameters that can influence atmospheric visibility, climate change and human health. Based on continuous field measurements of inorganic aerosol species and their thermodynamic modeling on a time resolution of 1h, this study has investigated the acidic properties of PM2.5 and their relation with the formation of secondary inorganic aerosols (SIA).
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
May 2012
Introduction: The kinetics of the transformation of ammonia and acid gases into components of PM(2.5) has been examined. The interactions of existing aerosols and meteorology with the transformation mechanism have also been investigated.
View Article and Find Full Text PDFTo investigate the potential role of ammonia in ion chemistry of PM(2.5) aerosol, measurements of PM(2.5) (particulate matter having aerodynamic diameter < 2.
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