[Cadmium and Arsenic Interactions During Co-adsorption onto Goethite].

Cadmium (Cd) and arsenic (As) are commonly co-adsorbed onto iron oxides in the soil environment, especially in south China. This study aimed to elucidate the regulatory mechanisms in determining the As(Ⅴ)-Cd(Ⅱ) interactions on a goethite interface after excluding pH interference. At pH 6.

Competitive and synergistic effects of phosphate and cadmium coadsorbed on goethite.

Soil acidification in southern China increases the environmental risk posed by heavy metals, especially cadmium (Cd), and has been accelerated by anthropic activities. Long-term fertilizer use increases the quantity of phosphate (P) in soils, which affects the biogeochemistry of heavy metals in soil environments. In this study, various analytical methods were used to investigate the critical mechanisms controlling P(V)-Cd(II) interactions with goethite (α-FeOOH, a typical iron oxide widely distributed in red soil areas) with added P(V)/Cd(II) in different molar ratios (to simulate the annual P fertilizer surplus).

Occurrence of organophosphate esters and their diesters degradation products in industrial wastewater treatment plants in China: Implication for the usage and potential degradation during production processing.

Influent, effluent and sludge samples were collected from eight industrial wastewater treatment plants (WWTPs) in the Pearl River Delta, China. Samples were investigated for the occurrence of 10 organophosphate esters (OPEs) and 7 organophosphate diesters (Di-OPs). Most of the 10 OPEs were detected at total concentrations of OPEs (∑OPEs) ranging from 65.