Break-up and mobilization of DNAPL by acoustic excitation: Experimental evidence and pore network modeling.

Dense non-aqueous phase liquids (DNAPLs) are long-term groundwater contaminants due to their high toxicity and slight solubility in water. The use of acoustic waves to remobilize trapped ganglia in subsurface porous systems have some advantages over pre-existing solutions including eliminating the bypassing effect and new environmental hazards. Designing an effective acoustically assisted remediation method for such purposes relies on understanding the underlying mechanisms and developing validated models.

Remediation of trapped DNAPL enhanced by SDS surfactant and silica nanoparticles in heterogeneous porous media: experimental data and empirical models.

The remediation of nonaqueous phase liquids (NAPLs) enhanced by surfactant and nanoparticles (NP) has been investigated in numerous studies. However, the role of NP-assisted surfactants in the dissolution process is still not well discussed. Besides, there is a lack of empirical dissolution models considering the effects of initial residual saturation S, NAPL distribution, and surfactant concentration in NAPL-aqueous phase systems.

Experimentally based pore network modeling of NAPL dissolution process in heterogeneous porous media.

Practical designs of non-aqueous phase liquids (NAPLs) remediation strategies require reliable modeling of interphase mass transfer to predict the retraction of NAPL during processes such as dissolution. In this work, the dissolution process of NAPL during two-phase flow in heterogeneous porous media is studied using pore-network modeling and micromodel experiments. A new physical-experimental approach is proposed to enhance the prediction of the dissolution process during modeling of interphase mass transfer.