Microplastics: unraveling the signaling pathways involved in reproductive health.

Microplastics (MPs) are biologically active environmental pollutants having significant impact on the ecosystem and human health. MPs have been reported to increase oxidative stress, resulting in tissue damage, developmental abnormalities, metabolic disorders, epigenetic changes, abnormal reproduction, and reduced gamete quality. At present, most of the existing literature has focused on the effects of MPs on the reproduction of various aquatic organisms; however, the effects of MPs on mammalian reproduction specifically humans are least studied except a few ones fragmentally discussing the effects of MPs on gametogenesis in human.

Analysis of base content in in-service oils by fourier transform infrared spectroscopy.

An automated FTIR method for the determination of the base content (BC(pKa)) of oils at rates of > 120 samples/h has been developed. The method uses a 5% solution of trifluoroacetic acid in 1-propanol (TFA/P) added to heptane-diluted oil to react with the base present and measures the ν(COO(-)) absorption of the TFA anion produced, with calibrations devised by gravimetrically adding 1-methylimidazole to a heptane-TFA/P mixture. To minimize spectral interferences, all spectra are transformed to 2(nd) derivative spectra using a gap-segment algorithm.

Simultaneous mobilization of macro- and trace elements (MTEs) and polycyclic aromatic hydrocarbon (PAH) compounds from soil with a nonionic surfactant and [S,S]-ethylenediaminedisuccinic acid (EDDS) in admixture: PAH compounds.

A laboratory study was conducted to assess the feasibility of a washing process with nonionic surfactant in combination with EDDS for the simultaneous mobilization of MTEs and PAH compounds from a field-contaminated soil. Unit processes consisting of complexometric extraction and surfactant-assisted mobilization were combined with reagent regeneration and detoxification steps to generate innocuous products. Thirty minutes of ultrasonic mixing of the soil with a combination of 20 mL L(-1) surfactant suspension and a sparing quantity (2 mmol) of EDDS mobilized virtually all of the benzo[α] pyrene (B(a)P) and chrysene (Cry) and an appreciable portion of the burdens of Cd, Cr, Mn, Ni, Pb and Zn, lesser amounts of the As and Cu, but only small quantities of Al and Fe.

Simultaneous mobilization of heavy metals and polychlorinated biphenyl (PCB) compounds from soil with cyclodextrin and EDTA in admixture.

This study evaluated the efficacy of a washing process with cyclodextrin in combination with ethylenediaminetetraacetate (EDTA) for the simultaneous mobilization of heavy metals and PCBs from a field contaminated soil. Ultrasonically aided mixing of the field contaminated soil with a combination of cyclodextrin solution (10%, w/v) and a sparing quantity (2 mmol) of EDTA, simultaneously mobilized appreciable quantities of PCBs and much of the analyte metal (Cd, Cr, Cu, Mn, Ni, Pb, Zn) burdens. Relative to the action of individual reagents, a combination of randomly methylated (RAMEB) or hydroxypropyl beta-cyclodextrin (HPCD) with EDTA did not alter the PCB extraction efficiency nor did the presence of cyclodextrin change the efficiency of mobilization of most heavy metals (Al, Cd, Cr, Fe, Mn, Ni, and Zn) but did increase the recovery of Cu and Pb modestly.

A washing procedure to mobilize mixed contaminants from soil: I. Polychlorinated biphenyl compounds.

We conducted a laboratory study to assess the feasibility of a washing process with nonionic and anionic surfactants in combination with ethylenediaminetetraacetate (EDTA) for the simultaneous mobilization of heavy metals and polychlorinated biphenyls (PCBs) from a field-contaminated soil. Unit processes consisting of complexometric extraction and surfactant-assisted mobilization were combined with reagent regeneration and detoxification steps to generate innocuous products. Ten minutes of ultrasonic mixing of the soil with a combination of 30 mL L(-1) surfactant suspension and a sparing quantity (2 mmol) of EDTA mobilized appreciable quantities of PCBs, virtually all of the available Cd, Cu, Mn, and Pb, and lesser amounts of the Zn, Ni, and Cr but only small quantities of Al and Fe.

A washing procedure to mobilize mixed contaminants from soil: II. Heavy metals.

We conducted a laboratory study to assess the efficiency of nonionic and anionic surfactants in combination with a sparing quantity of ethylenediaminetetraacetate (EDTA) to simultaneously extract heavy metals (HMs) and polychlorinated biphenyl (PCB) compounds from a field-contaminated soil. A soil wash that mobilized both HMs and PCBs was combined with back-extraction with hexane to remove PCBs from the aqueous wash. The aqueous washing suspension was then regenerated by precipitation of the HMs induced by corrosion and hydrolysis of zero-valent Mg to provide a cleaned soil and innocuous extract.

Estimates of total polychlorinated biphenyl (PCB) compounds in soils/sediments by hydrogenolysis to dicyclohexyl.

A method to determine the total PCB content by hydrogenolysis (hydrodechlorination and hydrogenation) of chlorinated biphenyl compounds was extended to natural particulate matrices (soil and sediment). The contaminated soil was suspended in hexane in the presence of Pd/gamma-Al2O3 in a hydrogen atmosphere then permitted to react for one hour at 65 degrees C. Dicyclohexyl, recovered in the hexane, was quantified by gas chromatography mass spectrometry.