The climate benefits from cement carbonation are being overestimated.

Rapid decarbonization of the cement industry is critical to meeting climate goals. Oversimplification of direct air capture benefits from hydrated cement carbonation has skewed the ability to derive decarbonization solutions. Here, we present both global cement carbonation magnitude and its dynamic effect on cumulative radiative forcing.

Technical, economic, and environmental feasibility of rice hull ash from electricity generation as a mineral additive to concrete.

A circular economy based on symbiotic relationships among sectors, where the waste from one is resource to another, holds promise for cost-effective and sustainable production. This research explores such a model for the agriculture, energy, and construction sectors in California. Here, we develop new an understanding for the synergistic utilization mechanisms for rice hull, a byproduct from rice production, as a feedstock for electricity generation and rice hull ash (RHA) used as a supplementary cementitious material in concrete.

Predicting biochar properties and pyrolysis life-cycle inventories with compositional modeling.

Biochar, formed through slow pyrolysis of biomass, has garnered attention as a pathway to bind atmospheric carbon in products. However, life cycle assessment data for biomass pyrolysis have limitations in data quality, particularly for novel processes. Here, a compositional, predictive model of slow pyrolysis is developed, with a focus on CO fluxes and energy products, reflecting mass-weighted cellulose, hemicellulose, and lignin pyrolysis products for a given pyrolysis temperature.

Harmonized Life-Cycle Inventories of Nanocellulose and Its Application in Composites.

Cellulose nanocrystals (CNC) and nanofibers (CNF) have been broadly studied as renewable nanomaterials for various applications, including additives in cement and plastics composites. Herein, life cycle inventories for 18 previously examined processes are harmonized, and the impacts of CNC and CNF production are compared with a particular focus on GHG emissions. Findings show wide variations in GHG emissions between process designs, from 1.

Near-term pathways for decarbonizing global concrete production.

Growing urban populations and deteriorating infrastructure are driving unprecedented demands for concrete, a material for which there is no alternative that can meet its functional capacity. The production of concrete, more particularly the hydraulic cement that glues the material together, is one of the world's largest sources of greenhouse gas (GHG) emissions. While this is a well-studied source of emissions, the consequences of efficient structural design decisions on mitigating these emissions are not yet well known.

Cement substitution with secondary materials can reduce annual global CO emissions by up to 1.3 gigatons.

Population and development megatrends will drive growth in cement production, which is already one of the most challenging-to-mitigate sources of CO emissions. However, availabilities of conventional secondary cementitious materials (CMs) like fly ash are declining. Here, we present detailed generation rates of secondary CMs worldwide between 2002 and 2018, showing the potential for 3.

Environmental Impacts of Alternative Cement Binders.

Cement production is among the most difficult industrial activities to decarbonize. Various measures have been proposed and explored to reduce its CO emissions. Among these measures, the substitution of portland cement (PC) clinker with alternative materials is arguably the most effective, and consequently is an area of high research and commercial interest.