Midinfrared Cavity-Enhanced Two-Photon Absorption Spectroscopy for Selective Detection of Trace Gases.

Detection of trace gases, such as radioactive carbon dioxide, clumped isotopes, and reactive radicals, is of great interest and poses significant challenges in various fields. Achieving both high selectivity and high sensitivity is essential in this context. We present a highly selective molecular spectroscopy method based on comb-locked, mid-infrared, cavity-enhanced, two-photon absorption.

Network pharmacology‑based analysis and experimental verification of the inhibitory role of luteoloside on gastric cancer cells via the p53/p21 pathway.

The present study aimed to investigate the inhibitory effect of luteoloside on the proliferation, migration and invasion of gastric cancer (GC) cells based on network pharmacology and experiments. GC-associated targets were obtained from the GeneCards and Online Mendelian Inheritance in Man databases. Gene Ontology functional enrichment analysis and Kyoto Encyclopedia of Genes and Genomes pathway enrichment analysis were performed using the Database for Annotation, Visualization and Integrated Discovery.

Profiling a pulsed molecular beam with cavity-enhanced absorption spectroscopy.

The molecular beam plays an important role in chemical dynamics experiments. The density in the beam is one of the critical factors influencing the reaction rate in these studies. Here we present a method based on laser-locked cavity-enhanced absorption spectroscopy to measure the molecular density in the beam.

Preparation of High Vibrational States in the Entire Molecular Beam.

Preparing highly excited molecules is of great interest in chemistry, but it has long been a challenge due to the high laser power required within the narrow line width to excite a weak transition. We present a cavity-enhanced infrared excitation scheme using a milliwatt laser. As a demonstration, about 35% of CO molecules in a ground-state rotational level were excited to the highly excited = 3 state in the entire pulsed supersonic beam, as confirmed by the depletion of molecules in the ground state.

Mid-infrared Doppler-free saturation absorption spectroscopy of the Q branch of CHν= 1 band using a rapid-scanning continuous-wave optical parametric oscillator.

We have developed a mid-infrared Doppler-free saturation absorption spectroscopy apparatus that employs a commercial continuous-wave optical parametric oscillator (CW OPO), complemented by a home-built automation and wavelength scanning system. Here, we report a comprehensive spectral scan of the Q branch transitions of the ν= 1 band of methane (CH) with an average linewidth (FWHM) of 4.5 MHz.

The P2 protein of wheat yellow mosaic virus acts as a viral suppressor of RNA silencing in Nicotiana benthamiana to facilitate virus infection.

Wheat yellow mosaic virus (WYMV) causes severe viral wheat disease in Asia. The WYMV P1 protein encoded by RNA2 has viral suppressor of RNA silencing (VSR) activity to facilitate virus infection, however, VSR activity has not been identified for P2 protein encoded by RNA2. In this study, P2 protein exhibited strong VSR activity in Nicotiana benthamiana at the four-leaf stage, and point mutants P70A and G230A lost VSR activity.

Learning Virtual View Selection for 3D Scene Semantic Segmentation.

2D-3D joint learning is essential and effective for fundamental 3D vision tasks, such as 3D semantic segmentation, due to the complementary information these two visual modalities contain. Most current 3D scene semantic segmentation methods process 2D images "as they are", i.e.

Rovibrational Energies of CO Determined with Kilohertz Accuracy.

Accurate spectroscopic data of carbon dioxide are widely used in many important applications, such as carbon monitoring missions. Here, we present comb-locked cavity ring-down saturation spectroscopy of the second most abundant isotopologue of CO, CO. We determined the positions of 88 lines in three vibrational bands in the 1.

Mid-infrared-near-infrared double-resonance spectroscopy of molecules with kilohertz accuracy.

Precision measurements of molecular transitions to highly excited states are needed in potential energy surface modeling, state-resolved chemical dynamics studies, and astrophysical spectra analysis. Selective pumping and probing of molecules are often challenging due to the high state density and weak transition moments. We present a mid-infrared and near-infrared double-resonance spectroscopy method for precision measurements.

Different delocalized ranges in mixed valence cyanido-metal-bridged Fe-Ru-Fe complexes controlled by terminal ligand substitution modification.

In order to investigate the properties of metal to metal charge transfer (MMCT) influenced by the relative energy level between the bridging unit and the terminal unit, two groups of heterotrimetallic cyanido-metal-bridged complexes, -[Cp(dppe)Fe-CN-Ru(MeOpy)-NC-Fe(dppe)Cp][X] (1[X]n; = 2, 3, or 4; X = PF or BF) (Cp = cyclopentadiene, dppe = 1,2-bis(diphenylphosphino)ethane, MeOpy = 4-methoxypyridine) and [Cp*(dppe)Fe-CN-Ru(MeOpy)-NC-Fe(dppe)Cp*] [X] (2[X]n; Cp* = 1,2,3,4,5-pentamethylcyclopentadiene; = 2, 3, or 4; X = PF or BF) were synthesized and fully characterized. The crystallography data suggest different oxidation sites in the ground state for one-electron oxidation products 13+ and 23+, and the electrochemical and Mössbauer spectra suggest that in the one-electron oxidation compounds 13+, the charge is delocalized all along the trimetal backbone Fe-Ru-Fe, while in 23+, the charge is rather delocalized between the two metal parts Fe-Ru. Further oxidation of N3+ gives N4+ ( = 1 or 2), during which a spin transfer towards the terminal units is observed in both series.

Anti-factor Xa level monitoring of low-molecular-weight heparin for prevention of venous thromboembolism in critically ill patients (AXaLPE): protocol of a randomised, open-label controlled clinical trial.

Introduction: Whether and when to monitor the amount of anti-factor Xa (aFXa) activity in critically ill patients with complex diseases to prevent venous thromboembolism (VTE) remain unclear. This study is a randomised controlled trial to investigate the effect of aFXa level monitoring on reducing VTE and to establish a new method for accurately preventing VTE in critically ill patients with low-molecular-weight heparin (LMWH).

Methods And Analysis: A randomised controlled trial is planned in two centres with a planned sample size of 858 participants.

Precision spectroscopy of molecular hydrogen.

Precision measurements on the hydrogen molecule are of fundamental importance in understanding molecular theory. Comparison of accurate experimental data and theoretical results are used to test the quantum electrodynamics theory and determine physical constants used in the calculation. We review recent advances and perspectives in the precision spectroscopy of molecular hydrogen, representing state-of-the-art molecular spectroscopy methods and cutting-edge high-precision calculations.

The P1 protein of wheat yellow mosaic virus exerts RNA silencing suppression activity to facilitate virus infection in wheat plants.

Wheat yellow mosaic virus (WYMV) causes severe wheat viral disease in Asia. However, the viral suppressor of RNA silencing (VSR) encoded by WYMV has not been identified. Here, the P1 protein encoded by WYMV RNA2 was shown to suppress RNA silencing in Nicotiana benthamiana.

Pickering emulsions stabilized by soybean protein isolate/chitosan hydrochloride complex and their applications in essential oil delivery.

In this work, fabrication of soybean protein isolate (SPI)/chitosan hydrochloride (CHC) composite particles stabilized O/W Pickering emulsions using soybean oil as an oil phase was optimized by examining the effects of pH, SPI/CHC mass ratio, SPI/CHC composite particle concentration and oil phase fraction on the stability of the emulsions. The results showed that under the conditions of SPI/CHC mass ratio 1:1, pH 4 and particle concentration 2 %, the SPI/CHC composite particles could stabilize the emulsions with oil phase fraction up to 80 %. At an oil phase fraction of 60 %, the emulsions had a minimum particle size.

Metal-Metal Charge Transfer Properties of a Series of Trinuclear Fe Ru and Corresponding Pentanuclear Fe Ru Ag Cyanido-Bridged Complexes.

A series of trimetallic cyanidometal-bridged compounds [Me Cp(dppe)Fe -(μ-NC)-Ru (MeOpy) -(μ-CN)-Fe (dppe)CpMe ] - [PF ] (N[PF ] , n=0, N =1; n=1, N=2; n=3, N=3; Cp=cyclopentadiene, dppe=1,2-bis(diphenylphosphino)ethane, MeOpy=4-methoxypyridine) and their one- and two-electron oxidized compounds N and N were synthesized and characterized. Meanwhile, a series of corresponding linear cyanido-bridged pentanuclear compounds [Me Cp(dppe)Fe -(μ-NC)-Ru (MeOpy) -(μ-NC)-Ag -(μ-CN)-Ru (MeOpy) -(μ-CN)-Fe (dppe)CpMe ][BF ] (M[BF ] , n=0, M=4; n=1, M=5; n=3, M=6) were also obtained and well characterized. The investigations suggest that in the trinuclear system there exists remote interaction between the two Fe centers, but no significant interactions exist across the central silver unit between the metals on the two sides of the silver center in the pentanuclear system.

LC-NeRF: Local Controllable Face Generation in Neural Radiance Field.

3D face generation has achieved high visual quality and 3D consistency thanks to the development of neural radiance fields (NeRF). However, these methods model the whole face as a neural radiance field, which limits the controllability of the local regions. In other words, previous methods struggle to independently control local regions, such as the mouth, nose, and hair.

Measurement-Device-Independent Quantum Key Distribution Based on Decoherence-Free Subspaces with Logical Bell State Analyzer.

Measurement-device-independent quantum key distribution (MDI-QKD) enables two legitimate users to generate shared information-theoretic secure keys with immunity to all detector side attacks. However, the original proposal using polarization encoding is sensitive to polarization rotations stemming from birefringence in fibers or misalignment. To overcome this problem, here we propose a robust QKD protocol without detector vulnerabilities based on decoherence-free subspaces using polarization-entangled photon pairs.