Sub-pixel high-resolution imaging of high-energy x-rays inspired by sub-wavelength optical imaging.

We have developed and demonstrated an image super-resolution method-XR-UNLOC: X-Ray UNsupervised particle LOCalization-for hard x-rays measured with fast-frame-rate detectors that is an adaptation of the principle of photo-activated localization microscopy (PALM) and stochastic optical reconstruction microscopy (STORM), which enabled biological fluorescence imaging at sub-optical-wavelength scales. We demonstrate the approach on experimental coherent Bragg diffraction data measured with 52 keV x-rays from a nanocrystalline sample. From this sample, we resolve the fine fringe detail of a high-energy x-ray Bragg coherent diffraction pattern to an upsampling factor of 16 of the native pixel pitch of 30 μm of a charge-integrating fastCCD detector.

Submicron focusing of high-energy X-rays with silicon saw-tooth refractive lenses - fabrication and aberrations: errata.

Three (3) items of errata are submitted for our recently published paper [Opt. Express28, 36505 (2020)10.1364/OE.

Submicron focusing of high-energy X-rays with silicon saw-tooth refractive lenses: fabrication and aberrations.

Saw-tooth refractive lenses are extremely well-suited to focus high energy X-rays (>50 keV). These lenses have properties of being continuously tunable (in energy or focal length), effectively parabolic, in-line, and attenuation-free on-axis. Vertical focusing of 60 keV synchrotron X-rays to 690 nm at a focal length f = 1.

Focusing with saw-tooth refractive lenses at a high-energy X-ray beamline.

The Advanced Photon Source 1-ID beamline, operating in the 40-140 keV X-ray energy range, has successfully employed continuously tunable saw-tooth refractive lenses to routinely deliver beams focused in both one and two dimensions to experiments for over 15 years. The practical experience of implementing such lenses, made of silicon and aluminium, is presented, including their properties, control, alignment, and diagnostic methods, achieving ∼1 µm focusing (vertically). Ongoing development and prospects towards submicrometre focusing at these high energies are also mentioned.

Enhancement of lanthanide evaporation by complexation: dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide.

The vapors in equilibrium with condensates of DyI3, DyI3/InI, TmI3, and TmI3/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI3/InI and TmI3/TlI as compared to the vapors over pure DyI3 and pure TmI3, respectively.

Synchrotron Mössbauer spectroscopy using high-speed shutters.

A new method of performing Mössbauer spectroscopy with synchrotron radiation is demonstrated that involves using a high-speed periodic shutter near the focal spot of a microfocused X-ray beam. This fast microshuttering technique operates without a high-resolution monochromator and has the potential to produce much higher signal rates. It also offers orders of magnitude more suppression of unwanted electronic charge scattering.

Melting of Bi sublattice in nanosized BiFeO3 Perovskite by resonant X-ray diffraction.

Free-standing BiFeO3 perovskite particles with a size ranging from polycrystalline bulk down to 5 nm have been studied by high-energy resonant (Bi K edge) x-ray diffraction coupled to differential atomic pair distribution function analysis. Nanosized BiFeO3 particles are found to exhibit extra, i.e.

Silicon saw-tooth refractive lens for high-energy X-rays made using a diamond saw.

Silicon is a material well suited for refractive lenses operating at high X-ray energies (>50 keV), particularly if implemented in a single-crystal form to minimize small-angle scattering. A single-crystal silicon saw-tooth refractive lens, fabricated by a dicing process using a thin diamond wheel, was tested with 115 keV X-rays, giving an ideal 17 microm line focus width in a long focal length, 2:1 ratio demagnification geometry, with a source-to-focus distance of 58.5 m.

High-energy X-ray optics with silicon saw-tooth refractive lenses.

Silicon saw-tooth refractive lenses have been in successful use for vertical focusing and collimation of high-energy X-rays (50-100 keV) at the 1-ID undulator beamline of the Advanced Photon Source. In addition to presenting an effectively parabolic thickness profile, as required for aberration-free refractive optics, these devices allow high transmission and continuous tunability in photon energy and focal length. Furthermore, the use of a single-crystal material (i.

Polyamorphism in a metallic glass.

A metal, or an alloy, can often exist in more than one crystal structure. The face-centred-cubic and body-centred-cubic forms of iron (or steel) are a familiar example of such polymorphism. When metallic materials are made in the amorphous form, is a parallel 'polyamorphism' possible? So far, polyamorphic phase transitions in the glassy state have been observed only in glasses involving directional and open (such as tetrahedral) coordination environments.

Formation and subdivision of deformation structures during plastic deformation.

During plastic deformation of metals and alloys, dislocations arrange in ordered patterns. How and when these self-organization processes take place have remained elusive, because in situ observations have not been feasible. We present an x-ray diffraction method that provided data on the dynamics of individual, deeply embedded dislocation structures.

Experimental characterization of APS undulator A at high photon energies (50-200 keV).

The considerable intensity of Advanced Photon Source (APS) undulator A as a source of high-energy X-rays permits the performance of numerous types of experiments that require such photon energies. Measured and calculated properties, in the 50-200 keV range, of the X-ray beam from undulator A, installed in sector 1 of the APS, are presented. The flux spectra observed at various gaps agree well with calculations that incorporate the actual magnetic field within the device and the emittance and energy spread of the stored positrons.

Quantitative high-pressure pair distribution function analysis.

The collection of scattering data at high pressure and temperature is now relatively straightforward thanks to developments at high-brightness synchrotron radiation facilities. Reliable data from powders, that are suitable for structure determination and Rietveld refinement, are routinely collected up to about 30 GPa in either a large-volume high-pressure apparatus or diamond anvil cell. In those cases where the total elastic scattering is of interest, as it is in the case of nano-crystalline and glassy materials, technical developments, including the use of focused high-energy X-rays (>80 keV), are advantageous.

Probing local and long-range structure simultaneously: an in situ study of the high-temperature phase transition of alpha-AlF3.

We show in this Communication that the combination of Rietveld and pair distribution function (PDF) analyses allows unique insight into the nature and driving force of the phase transition of alpha-AlF3, which was not available from conventional structural analysis methods alone. The use of image plate technology allows structural changes to be followed in "real time" and reduces the time required to collect high-resolution PDF data from hours (with a conventional solid state detector) to seconds. This methodology produces raw data that can simultaneously be analyzed by both Rietveld and PDF analysis.

Combining flat crystals, bent crystals and compound refractive lenses for high-energy X-ray optics.

Compound refractive lenses (CRLs) are effective for collimating or focusing high-energy X-ray beams (50-100 keV) and can be used in conjunction with crystal optics in a variety of configurations, as demonstrated at the 1-ID undulator beamline of the Advanced Photon Source. As a primary example, this article describes the quadrupling of the output flux when a collimating CRL, composed of cylindrical holes in aluminium, is inserted between two successive monochromators, i.e.

Cryogenically cooled bent double-Laue monochromator for high-energy undulator X-rays (50-200 keV).

A liquid-nitrogen-cooled monochromator for high-energy X-rays consisting of two bent Si(111) Laue crystals adjusted to sequential Rowland conditions has been in operation for over two years at the SRI-CAT sector 1 undulator beamline of the Advanced Photon Source (APS). It delivers over ten times more flux than a flat-crystal monochromator does at high energies, without any increase in energy width (DeltaE/E approximately 10(-3)). Cryogenic cooling permits optimal flux, avoiding a sacrifice from the often employed alternative technique of filtration - a technique less effective at sources like the 7 GeV APS, where considerable heat loads can be deposited by high-energy photons, especially at closed undulator gaps.

Search for x-ray induced acceleration of the decay of the 31-yr isomer of (178)Hf using synchrotron radiation.

Enhanced decay of the 31-yr isomer of (178)Hf induced by x-ray irradiation has been reported previously. Here we describe an attempt to reproduce this result with an intense "white" x-ray beam from the Advanced Photon Source. No induced decay was observed.

Polyhedral units and network connectivity in calcium aluminosilicate glasses from high-energy X-Ray diffraction.

Structure factors for Ca (x/2)Al xSi 1-xO (2) glasses (x = 0,0.25,0. 5,0.