Acta Crystallogr B Struct Sci Cryst Eng Mater
October 2024
Magnetic materials featuring triangular arrangements of spins are frequently investigated as platforms hosting magnetic frustration. Hexagonal perovskites with ordered vacancies serve as excellent candidates for two-dimensional triangular magnetism due to the considerable separation of the magnetic planes. In this work, the effects of chemical pressure on the ferromagnetic ground state of BaLaNiWO by substitution of Ba with Sr to produce SrLaNiWO are investigated.
View Article and Find Full Text PDFFermi surfaces are essential for predicting, characterizing and controlling the properties of crystalline metals and semiconductors. Angle-resolved photoemission spectroscopy (ARPES) is the only technique directly probing the Fermi surface by measuring the Fermi momenta (k) from energy- and angular distribution of photoelectrons dislodged by monochromatic light. Existing apparatus is able to determine a number of k -vectors simultaneously, but direct high-resolution 3D Fermi surface mapping remains problematic.
View Article and Find Full Text PDFWe present a systematic study of the evolution of structural parameters and electronic correlations as a function of 3d band filling in a single crystal series of BaTAs (T = Cr-Cu). The structure trends are discussed in relation to the orbital occupation of the corresponding d elements supported by calculations of the charge density and electron localization function. Analysis of our specific heat data yields the mass enhancement (*/) throughout the series.
View Article and Find Full Text PDFWe report a systematic elastoresistivity study on LaFe_{1-x}Co_{x}AsO single crystals, which have well separated structural and magnetic transition lines. All crystals show a Curie-Weiss-like nematic susceptibility in the tetragonal phase. The extracted nematic temperature is monotonically suppressed upon cobalt doping, and changes sign around the optimal doping level, indicating a possible nematic quantum critical point beneath the superconducting dome.
View Article and Find Full Text PDFDownsizing well-established materials to the nanoscale is a key route to novel functionalities, in particular if different functionalities are merged in hybrid nanomaterials. Hybrid carbon-based hierarchical nanostructures are particularly promising for electrochemical energy storage since they combine benefits of nanosize effects, enhanced electrical conductivity and integrity of bulk materials. We show that endohedral multiwalled carbon nanotubes (CNT) encapsulating high-capacity (here: conversion and alloying) electrode materials have a high potential for use in anode materials for lithium-ion batteries (LIB).
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