Functionalization of three-dimensional epitaxial graphene with metal nanoparticles.

We demonstrate the first successful functionalization of epitaxial three-dimensional graphene with metal nanoparticles. The functionalization is obtained by immersing three-dimensional graphene in a nanoparticle colloidal solution. This method is versatile and demonstrated here for gold and palladium, but can be extended to other types of nanoparticles.

Correction: Covalent organic functionalization of graphene nanosheets and reduced graphene oxide 1,3-dipolar cycloaddition of azomethine ylide.

[This corrects the article DOI: 10.1039/D1NA00335F.].

Covalent organic functionalization of graphene nanosheets and reduced graphene oxide 1,3-dipolar cycloaddition of azomethine ylide.

Organic functionalization of graphene is successfully performed 1,3-dipolar cycloaddition of azomethine ylide in the liquid phase. The comparison between 1-methyl-2-pyrrolidinone and ,-dimethylformamide as dispersant solvents, and between sonication and homogenization as dispersion techniques, proves ,-dimethylformamide and homogenization as the most effective choice. The functionalization of graphene nanosheets and reduced graphene oxide is confirmed using different techniques.

A sensitive calorimetric technique to study energy (heat) exchange at the nano-scale.

Every time a chemical reaction occurs, an energy exchange between reactants and the environment takes place, which is defined as the enthalpy of the reaction. During the last few decades, research has resulted in an increasing number of devices at the micro- or nano-scale. Sensors, catalyzers, and energy storage systems are more and more developed as nano-devices which represent the building blocks for commercial "macroscopic" objects.