New 'side-off' coordination asymmetric homobinuclear Ni(II) and heterobinuclear Ni(II)Zn(II) complexes as models for hydrolysis of p-nitrophenylphosphate: synthesis, characterization and electrochemical studies.

A series of new phenol based coordination asymmetric side-off homobinuclear Ni(II) and heterobinuclear Ni(II)Zn(II) complexes have been synthesized and characterized by elemental analysis and spectral analysis. The electronic spectra of all the complexes show "Red shift" in LMCT band, for the ligand H(2)L(2) having electron donating C(2)H(5) groups as N-substituents in the free side arms compared to ligand H(2)L(1) having relatively lower electron donating CH(3) groups. Electrochemical studies of the complexes reveal that all the binuclear complexes show two irreversible one-electron transfer reduction waves in the cathodic region.

Synthesis and characterization of new unsymmetrical 'side-off' tetra and hexa coordinate homobinuclear Cu(II) and heterobinuclear Cu(II)-Zn(II) complexes: Magnetic, electrochemical and kinetic studies.

A new class of phenol based unsymmetrical side-off tetra and hexa coordinate homobinuclear Cu(II) and heterobinuclear Cu(II)-Zn(II) complexes have been synthesized and characterized by elemental and spectral analysis. The electronic spectra of all the complexes show "Red shift" in LMCT band, for the ligand H(2)L(2) compared to that of the ligand H(2)L(1) due to the relatively higher electron donating nature of their substitutents. The homobinuclear Cu(II) complexes (1 and 2) illustrate an antiferromagnetic interaction (μ(eff): 1.

Synthesis, characterization and bioactive evaluation of copper(II) 5,10,15,20-tetrakis[alpha,alpha,alpha,alpha-2-(2,6-bis(4-methylpiperazine-1-yl-methyl)-4-iminomethyl phenol)phenyl] porphyrin: a picket-fence porphyrin.

We are interested in constructing deeper small cavities by adding more bulky substituents at the ortho-phenyl positions of tetrakis(o-aminophenyl)porphyrin. The synthesis of picket-fence porphyrin is initiated by the preparation of the tetrakis(o-nitrophenyl)porphyrin followed by the nitro to amino reduction and subsequent condensation with Schiff base ligand to form imine linkages of porphyrin complexes. The synthesis and characterization of a new series of picket-fence porphyrins and their copper complexes are described.

N-benzoylated 1,4,8,11-tetraazacyclotetradecane and their copper(II) and nickel(II) complexes: spectral, magnetic, electrochemical, crystal structure, catalytic and antimicrobial studies.

A series of N-benzoylated cyclam ligands incorporating three different benzoyl groups 1,4,8,11-tetra-(benzoyl)-1,4,8,11-tetraazacyclotetradecane (L(1)), 1,4,8,11-tetra-(2-nitrobenzoyl)-1,4,8,11-tetraazacyclotetradecane (L(2)) and 1,4,8,11-tetra-(4-nitrobenzoyl)-1,4,8,11-tetraazacyclotetradecane (L(3)) and their nickel(II) and copper(II) complexes are described. Crystal structure of L(1) is also reported. The ligands and complexes were characterized by elemental analysis, electronic, IR, (1)H NMR and (13)C NMR spectral studies.

Electrochemical, catalytic and antimicrobial activities of N-functionalized cyclam based unsymmetrical dicompartmental binuclear nickel(II) complexes.

Five binuclear nickel(II) complexes have been prepared by simple Schiff base condensation of the compound 1,8-[bis(3-formyl-2-hydroxy-5-bromo)benzyl]-l,4,8,11-tetraazacyclotetradecane (L) with appropriate aliphatic or aromatic diamine, nickel(II) perchlorate and triethylamine. All the complexes were characterized by elemental and spectral analysis. Positive ion FAB mass spectra show the presence of dinickel core in the complexes.