We report on a direct measurement of the quantum diffusion of H atoms in solid molecular hydrogen films at T=0.7 K. We obtained a rate of pure spatial diffusion of H atoms in the H_{2} films, D^{d}=5(2)×10^{-17} cm^{2} s^{-1}, which was 2 orders of magnitude faster than that obtained from H atom recombination, the quantity used in all previous work to characterize the mobility of H atoms in solid H_{2}.
View Article and Find Full Text PDFWe describe the design and construction of an experimental cell for the study of free radicals in macroscopically thick films of solidified molecular and rare gases by 128 GHz Electron Spin Resonance (ESR) at temperatures below 1 K. The ESR resonator has an open Fabry-Pérot design, and its frequency can be tuned in situ by adjusting the spacing between the mirrors. The tuning mechanism consists of a piezo positioner and a stainless-steel edge-welded bellows, which can change the resonator frequency by at least 6 GHz.
View Article and Find Full Text PDFWe present an experimental study of the Dynamic Nuclear Polarization (DNP) of Si nuclei in silicon crystals of natural abundance doped with As in the temperature range 0.1-1 K and in a strong magnetic field of 4.6 T.
View Article and Find Full Text PDFWe report on an experimental observation of two phases of hydrogen atoms in solid H_{2} films at temperatures of 0.1-0.8 K, characterized by a large enhancement of the nuclear spin polarization compared to that given by Boltzmann statistics (p=0.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2017
We report on the first ESR study of atomic hydrogen and tritium stabilized in solid T and T:H matrices down to 70 mK. The concentrations of T atoms in pure T approached 2 × 10 cm (0.60%) and record-high concentrations of H atoms ∼1 × 10 cm (0.
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