The distinct roles of different chemical species are essential for the discovery of novel chemical transformations in organic synthesis. Here, we have designed a potential strategy for the synthesis of triarylmethanes (TRAMs) using the dual C(aryl)-alkylation process. This protocol was influenced by 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) as a pivotal reagent and proceeds through the selective para C-H functionalization method.
View Article and Find Full Text PDFVasa previa is a rare but potentially life-threatening condition to the fetus. Timely antenatal diagnosis and delivery by cesarean section (CS) can lead to a favorable outcome. Here, we report a case of recurrent pregnancy loss (G3A2) with vasa previa, which was diagnosed prenatally by ultrasound.
View Article and Find Full Text PDFMode division multiplexing technology has the potential to increase the channel capacity of a single wavelength carrier. Attaining cost-effective high-bandwidth-density devices with small footprints is a concern, and photonic crystal based devices are promising for ultra-small on-chip communications. This paper presents a 2D photonic crystal based mode division (de)multiplexer on a silicon on insulator platform.
View Article and Find Full Text PDFBackground: In practice, we encounter many young infertile women with poor ovarian reserve though ovarian reserve starts to decline after 35 years of age. One of the established risk factors for poor ovarian reserve in young women is endometriosis. There are other conditions that are reported to be associated which require further research.
View Article and Find Full Text PDFBackground And Aims: Flupirtine has been used for various chronic pain conditions, but its utility in the perioperative period as an analgesic is still inconclusive. This systematic review and meta-analysis aimed to assess the efficacy of flupirtine for postoperative pain.
Methods: PubMed, Embase and the Cochrane Central Register of Controlled Trials (CENTRAL) were explored for the randomised controlled trials (RCTs) which compared flupirtine with other analgesic/placebo for perioperative pain in adult patients undergoing surgery.