Quantifying effects of second-sphere cationic groups on redox properties of dimolybdenum quadruple bonds.

A series of four dimolybdenum paddlewheel complexes supported by anionic ,-dimethylglycinate (DMG) or zwitterionic ,,-trimethylglycine (TMG) ligands was synthesised to examine the effects of charged groups in the second coordination sphere on redox properties of MoMo bonds. An average shift in reduction potential of +35 mV per cationically charged group was measured, which is approximately half of what would be expected for an analogous mononuclear complex.

Lessons from recent theoretical treatments of Al-M bonds (M = Fe, Cu, Ag, Au) that capture CO.

Complexes with Al-M bonds (M = transition metal) have emerged as platforms for discovering new reaction chemistry either through cooperative bond activation behaviour of the heterobinuclear unit or by modifying the properties of the M site through its interaction with the Al centre. Therefore, elucidating the nature of Al-M bonding is critical to advancing this research area and typically involves careful theoretical modelling. This Frontier article reviews selected recent case studies that included theoretical treatments of Al-M bonds, specifically highlighting complexes capable of cooperative CO activation and focusing on extracting lessons particular to the Al-M sub-field that will inform future studies with theoretical/computational components.

Influence of Stroke-Onset Location on the Efficacy of Endovascular Thrombectomy: Comparison of Outcomes between In-Hospital versus Community-Onset Strokes.

Background And Purpose: Previous studies have suggested that patients experiencing an in-hospital stroke may face delays in treatment and worse outcomes compared with patients with community-onset strokes. However, most studies occurred when IV thrombolysis was the primary treatment. This study aimed to examine the outcomes of patients experiencing an in-hospital stroke in the endovascular thrombectomy era.

Voyaging of halogenated polycyclic aromatic hydrocarbons, an emerging group of pollutants, on micro-mesoplastics in the marine environment.

The limited existing research on the accumulation of hazardous chlorinated and brominated polycyclic aromatic hydrocarbons (ClPAHs and BrPAHs) in micro-mesoplastics (mMPs) motivated this investigation. We collected mMPs from the coastal environments of Sri Lanka and Japan. Out of 75 target compounds analyzed, 61 were detected, with total parent PAH concentrations reaching 16,300 and 1770 ng/g plastic in Sri Lanka and Japan, respectively.

Identification of Confusing Medicine Proprietary Names: Toward Safe Medicine Use-A Cross-Sectional Study in Sri Lanka.

Background: Look-alike sound-alike (LASA) medications have similar pronunciation (phonetic) and/or manifestation (orthographic), which could create confusion among users and challenge the safe use of medicines. The availability of foreign products in local markets aggravates the situation. This study was designed to examine the registered medicine proprietary names in Sri Lanka to discern the presence of similar medicine names in the industry.