Dual optical frequency combs have been a recurrent case of study over the last decade due to their wide use in a variety of metrology applications. Utilizing a single cavity laser to generate a dual comb reduces system complexity and facilitates suppression of common noise. However, a dual-comb regime in single cavity lasers tends to be more unstable and difficult to achieve.
View Article and Find Full Text PDFLevulinic acid is a key biorenewable platform molecule. Its current chemical production from sugars is plagued by limited yields, char formation and difficult separations. An alternative and selective route starting from muconic acid via simple heating in water at high temperature (180 °C) has been developed.
View Article and Find Full Text PDFSoliton rain is a bunch of small soliton pulses slowly drifting near the main pulse having the period of a round trip. For Er-doped fiber laser mode-locked by carbon nanotubes, for the first time, we demonstrate both experimentally and theoretically a new type of polarization attractors controllable by vector soliton rain. With adjusting the pump power, vector soliton rain takes the form of pulses with rotating states of polarization which enable transforming slowly evolving trajectories on the Poincaré sphere from the double-scroll spiral to the circle.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2022
Acetate serves as a renewable and easily installed leaving group for selective deoxygenation of phenolics (ArOH). Ni-catalyzed hydrodeacetoxylation of aryl acetates (Ar-OAc) with HBpin in a green carbonate solvent selectively delivers the corresponding deoxygenated arenes (ArH). The method is also applicable to highly challenging guaiacyl and syringyl acetates, leaving -OMe groups intact without arene reduction.
View Article and Find Full Text PDFFor coupled linear cavity-random fiber Raman lasers, for the first time, to the best of our knowledge, we demonstrate a new mechanism of emergence of the random pulses, with the anomalous statistics satisfying optical rogue waves' criteria experimentally. The rogue waves appear as a result of the coupling of two Raman cascades, namely, a linear cavity laser with a wavelength of 1.55 µm and a random laser with a wavelength nearly 1.
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