Optimization of algorithms for ion mobility calculations.

Ion mobility spectrometry (IMS) is increasingly employed to probe the structures of gas-phase ions, particularly those of proteins and other biological macromolecules. This process involves comparing measured mobilities to those computed for potential geometries, which requires evaluation of orientationally averaged cross sections using some approximate treatment of ion-buffer gas collisions. Two common models are the projection approximation (PA) and exact hard-spheres scattering (EHSS) that represent ions as collections of hard spheres.

Feasibility of higher-order differential ion mobility separations using new asymmetric waveforms.

Technologies for separating and characterizing ions based on their transport properties in gases have been around for three decades. The early method of ion mobility spectrometry (IMS) distinguished ions by absolute mobility that depends on the collision cross section with buffer gas atoms. The more recent technique of field asymmetric waveform IMS (FAIMS) measures the difference between mobilities at high and low electric fields.

Superfluid bose liquid with a suppressed BEC and an intensive pair coherent condensate as a model of 4He.

One introduces a model of the superfluid state of a Bose liquid with repulsion between bosons, in which at T=0, along with a weak single-particle Bose-Einstein condensate, there exists an intensive pair coherent condensate, analogous to the Cooper condensate in a Fermi liquid with attraction between fermions. A closed system of nonlinear integral equations for the normal and anomalous self-energy parts is solved numerically, and a quasiparticle spectrum is obtained, which is in good agreement with the experimental spectrum of elementary excitations in superfluid 4He. It is shown that the roton minimum in the spectrum is associated with the negative minimum of the Fourier component of the pair interaction potential.