Design of Clickable Aromatic Donor-Acceptor Pairs for Easy Installation onto Polymers.

New intrinsically unsymmetric aromatic donors (D) and acceptors (A) were designed to simplify the incorporation of a single reactive group. Naphthalene diimide (NDI) was desymmetrized by replacing one of the imide units with two nitro groups to yield 3,6-dinitronaphthalene monoimide (NMI(NO)); likewise, 3,6-dimethoxycarbazole (CBZ(OMe)) was designed as a 3-ring aromatic donor. Different derivatives of naphthalene monoimide (NMI) and carbazole (CBZ) were prepared, and charge-transfer complex formation between them was studied using NMR and UV-visible titrations; the estimated association constants () were compared with the common pair, NDI, and 1,5-dialkoxy naphthalene (DAN).

Evaluation of Temperature-Dependent Boundary Lubrication Behavior of Stearic Acid Using a Force-Controlled Tribometer.

A quick evaluation of the effectiveness of additives is important in lubricant formulation. In this study, we employed a friction-force measurement approach using a newly designed lateral force-controlled tribometer. This tribometer evaluates the lubricant properties under boundary lubrication.

A Polymer-Based Metallurgical Route to Produce Aluminum Metal-Matrix Composite with High Strength and Ductility.

In this investigation, an attempt was made to develop a new high-strength and high-ductility aluminum metal-matrix composite. It was achieved by incorporating ceramic reinforcement into the metal which was formed in situ from a polymer by pyrolysis. A crosslinked PMHS polymer was introduced into commercially pure aluminum via friction stir processing (FSP).

A Rare Cause of Diarrhea: Intestinal Spirochetosis in an HIV-Positive Patient.

Intestinal spirochetosis (IS) is a rare gastrointestinal infection with vague presenting symptoms. Diagnosis is confirmed histopathologically. Risk factors include homosexuality and HIV.

You are not lab rats at teaching hospitals: A systematic review of resident and fellow participation leads to improved colonoscopy.

Background: Participation in colonoscopies is an essential aspect of endoscopic training. The purpose of this study was to explore the impact of fellow/trainee participation on colonoscopy outcomes.

Methods: This meta-analysis was registered on the International Prospective Register of Systematic Reviews (PROSPERO).