The Identification of Cu-O-C Bond in Cu/MWCNTs Hybrid Nanocomposite by XPS and NEXAFS Spectroscopy.

The results of the research of a composite based on multi-walled carbon nanotubes (MWCNTs) decorated with CuO/CuO/Cu nanoparticles deposited by the cupric formate pyrolysis are discussed. The study used a complementary set of methods, including scanning and transmission electron microscopy, X-ray diffractometry, Raman, and ultrasoft X-ray spectroscopy. The investigation results show the good adhesion between the copper nanoparticles coating and the MWCNT surface through the oxygen atom bridge formation between the carbon atoms of the MWCNT outer graphene layer and the oxygen atoms of CuO and CuO oxides.

The Structure and Chemical Composition of the Cr and Fe Pyrolytic Coatings on the MWCNTs' Surface According to NEXAFS and XPS Spectroscopy.

The paper is devoted to the structure and properties of the composite material based on multi-walled carbon nanotubes (MWCNTs) covered with pyrolytic iron and chromium. Fe/MWCNTs and Cr/MWCNTs nanocomposites have been prepared by the metal organic chemical vapor deposition (MOCVD) growth technique using iron pentacarbonyl and bis(arene)chromium compounds, respectively. Composites structures and morphologies preliminary study were performed using X-ray diffraction, scanning and transmission electron microscopy and Raman scattering.

Mysterious long-living ultrahigh-pressure or secondary impact crisis.

High-pressure glass has attracted interest in terms of both its fundamental state under extreme conditions and its possible applications as an advanced material. In this context, natural impact glasses are of considerable interest because they are formed under ultrahigh-pressure and high-temperature (UHPHT) conditions in larger volumes than laboratory fabrication can produce. Studying the UHPHT glasses of the unique giant Kara astrobleme (Russia), we found that the specific geological position of the UHPHT melt glass veins points to an origin from a secondary ultrahigh-pressure (UHP) melt according to the characteristics of the host suevites, which suggest later bottom flow.

Spectroscopic features of ultrahigh-pressure impact glasses of the Kara astrobleme.

The state of substances under ultrahigh pressures and temperatures (UHPHT) now raises a special interest as a matter existing under extreme conditions and as potential new material. Under laboratory conditions only small amounts of micrometer-sized matter are produced at a pressure up to 100 GPa and at room temperature. Simultaneous combination of ultrahigh pressures and temperatures in a lab still requires serious technological effort.