Differences/similarities of supramolecular motifs are discussed in two new thiophosphoramide structures and their Ni molecular complexes: (CHO)P(S)(NHC(S)NHCHCHX) and [{(CHO)P(S)(NC(S)NHCHCHX)}Ni] (X = Cl/CHI/II and III/IV). The structures have equal numbers of donor/acceptor sites contributing to classical hydrogen bonds (PS/CS and 2 × NH in ligands and 2 × PS and 2 × NH in the complexes). However, these donor and acceptor sites contribute to inter/intramolecular hydrogen bonding in ligands and intramolecular hydrogen bonding in complexes.
View Article and Find Full Text PDFThis protocol outlines a comprehensive approach to evaluating hospital solid waste levels and assessing associated health, safety, and environmental (HSE) risks using the Failure Mode and Effects Analysis (FMEA) methodology. The study focuses on Imam Khomeini Hospital (RA) and employs both quantitative and qualitative methods. Over a 3-month period, waste production and potential risks are assessed, with specific attention to household, infectious, medicinal, and sharps waste.
View Article and Find Full Text PDFToday, the main goal of many researchers is the use of high-performance, economically and industrially justified materials, as well as recyclable materials in removing organic and dangerous pollutants. For this purpose, sol-gel derived carbon aerogel modified with nickel (SGCAN) was used to remove Cefixime from aqueous solutions. The influence of important parameters in the cefixime adsorption onto SGCAN was modeled and optimized using artificial neural network (ANN), response surface methodology (RSM), genetic algorithm (GA), and SOLVER methods.
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