Storing and transporting pressurized or liquid hydrogen is expensive and hazardous. As a result, safer methods, such as chemical storage in ammonia, are becoming increasingly important. However, the instantaneous start of a conventionally heated decomposition reactor is challenging.
View Article and Find Full Text PDFPlatinum particle growth during long-term operations is one of the well-known bottlenecks offsetting the performance and stability of Pt-based electrocatalysts in polymer electrolyte membrane (PEM) fuel cells and PEM water electrolyzers. In this research, the addition of certain ceramic nanoparticulate additives to the catalyst ink was evaluated as a means of improving the electrochemical stability of a carbon-supported platinum (Pt/C) electrocatalyst in gas diffusion electrodes (GDEs) during an accelerated stress test (AST). GDEs prepared using three nanoparticulate ceramic additives (TiN, ATO, and TiO) with three loadings (replacing 5, 10, and 15 wt % of the catalyst) were studied for their electrochemical performance, i.
View Article and Find Full Text PDFEnhancing iridium (Ir)-based electrocatalysts to achieve high activity and robust durability for the oxygen evolution reaction (OER) in acidic environments has been an ongoing mission in the commercialization of proton exchange membrane (PEM) electrolyzers. In this study, we present the synthesis of carbon-supported Ir nanoparticles (NPs) using a modified impregnation method followed by solid-state reduction, with Ir loadings of 20 and 40 wt % on carbon. Among the catalysts, the sample with an Ir loading of 20 wt % synthesized at 1000 °C with a heating rate of 300 °C/h demonstrated the highest mass-normalized OER performance of 1209 A g and an OER current retention of 80% after 1000 cycles of cyclic voltammetry (CV).
View Article and Find Full Text PDFExamining the critical role of anticoagulants in medical practice, particularly their central function in preventing abnormal blood clotting, is of the utmost importance. However, the study of interactions between blood proteins and alternative anticoagulant nano-surfaces is still understood poorly. In this study, novel approach involving direct functionalisation of magnetic iron oxide nanoparticles (MNPs) as carriers with sulphated dextran (s-dext) is presented, with the aim of evaluating the potential of magnetically-responsive MNPs@s-dext as anticoagulants.
View Article and Find Full Text PDFElectrochemical water splitting under acidic conditions is a clean way towards producing hydrogen fuels. The slow kinetics of the oxygen evolution reaction (OER) at the anode is currently a bottleneck for commercial acceptance of this technology. Therefore, arriving at more efficient and sustainable OER electrocatalysts is highly desirable.
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