Influence of Organic Matter and Speciation on the Dynamics of Trace Metal Adsorption on Microplastics in Marine Conditions.

Dissolved organic matter (DOM), primarily in the form of humic acid (HA), plays a crucial role in trace metal (TM) speciation and their subsequent adsorption dynamics on microplastics (MP) in aquatic environments. This study evaluates the impact of environmentally relevant concentrations of HA on the adsorption behaviors of essential (Co, Cu, Ni, and Zn) and toxic (Cd and Pb) TMs onto polyethylene (PE) and polypropylene (PP) pellets, as well as PP fibers under marine conditions, during a six-week experiment. The HA concentrations were 0.

Potentially toxic elements in sediments near mines-a comprehensive approach for the assessment of pollution status and associated risk for the surface water environment.

This research is focused on the assessment of the pollution status of river and lake sediments near Pb, Zn, and Cu mines and tailings in the southeastern part of Serbia-Krajište area. The study is based on hypothesis that investigated rivers and lakes in the Krajište area could be polluted by potentially toxic elements (PTEs) and that these elements could pose considerable ecological risk to the studied surface water environment. High PTE contents are detected in studied river sediments (up to 7892 mg kg for Zn, 3224 mg kg for Cu, 36,790 mg kg for Pb, 64.

Correlation of metals and degraded marine (micro)plastic litter in geologically similar coastal areas with different anthropogenic characteristics.

The association and statistical correlation of anthropogenically important trace metals (TM) Cd, Cu, Pb, Zn and degraded marine microplastic (MP) extracted from the bulk debris samples at two locations from two marine systems, estuarine and coastal, in the Croatian Adriatic coastal area were assessed. The abundance of MP particles at both sites were primarily defined by local wave climate, with the open coastal site containing 9-fold more microplastic particles (>4 mm) as compared to the semi-closed estuarine, or twice as much considering bulk plastics. Generally, the higher abundance of adsorbed metal on MP were observed in the more anthropogenically influenced estuary than in the open coastal site and followed the order: polystyrene > polypropylene > low density polyethylene.

Assessing element distribution and speciation in a stream at abandoned Pb-Zn mining site by combining classical, in-situ DGT and modelling approaches.

The distribution and speciation of elements along a stream subjected to neutralised acid mine drainage (NAMD) effluent waters (Mátra Mountain, Hungary; Toka stream) were studied by a multi-methodological approach: dissolved and particulate fractions of elements were determined by HR-ICPMS, whereas speciation was carried out by DGT, supported by speciation modelling performed by Visual MINTEQ. Before the NAMD discharge, the Toka is considered as a pristine stream, with averages of dissolved concentrations of elements lower than world averages. A considerable increase of element concentrations caused by effluent water inflow is followed by a sharp or gradual concentration decrease.

Metal contamination recorded in the sediment of the semi-closed Bakar Bay (Croatia).

This study presents metal levels in the sediments of the Bakar Bay, with its main goal to evaluate recent anthropogenic influence, as well as over previous decades. Sediment profiles at 7 sampling points were taken. Chemical contents in bulk sediment were obtained using ICP, ICP-MS, and AAS methodologies, and 20 most significant elements were presented.