Green Synthesis of the Triazine Derivatives and their Application for the Benign Electrocatalytic Reaction of Nitrate Reduction to Ammonia.

This work uses green sustainable reactions twice. Firstly, it is microwave synthesis: 2,4,6-tribiphenyl-4-yl-1,3,5-triazine and similar compounds were prepared in a closed microwave reactor in n-octane by the Friedel-Crafts reaction. Second, a hybrid electrocatalyst for the highly demanded electrochemical reaction of nitrate reduction to ammonia (NORR) was prepared based on this material.

A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts.

The reaction of pyridine with cyanuric chloride was studied under microwave activation as well as in the presence of silver nitrate. The product of hydrolysis containing two pyridinium rings and chloride anion was isolated. The structures of these anion exchanger salts with chloride, nitrate and perrhenate anions are discussed.

Influence of the Method of Fe Deposition on the Surface of Hydrolytic Lignin on the Activity in the Process of Its Conversion in the Presence of CO.

Hydrolytic lignin is one of the non-demanded carbon materials. Its CO-assisted conversion is an important way to utilize it. The use of the catalysts prepared by metal deposition on the surface of hydrolytic lignin makes it possible to apply milder conditions of the conversion process with CO and to improve the economic indicators.

IR-spectroscopic study of complex formation of nitrogen oxides (NO, NO) with strong Lewis acid sites and the reactivity of adsorbed species in CO and CH oxidation.

The formation of complexes and transformations of nitrogen oxides (NO, NO) on strong Lewis acid sites of HZSM-5, H[Ga]ZSM-5, ZnO/HZSM-5 zeolites and dealuminated mordenites was investigated by diffuse-reflectance IR spectroscopy. Adsorbed NO that is formed by disproportionation of NO is capable of oxidizing CO and CH molecules to CO. The behaviour of strong Lewis acid sites in zeolites and cationic forms of zeolites in the NO disproportionation and CO or CH oxidation was comparatively studied.

Nitrous Oxide Adsorption and Decomposition on Zeolites and Zeolite-like Materials.

Decomposition of NO on modified zeolites, crystalline titanosilicalites, and related amorphous systems is studied by the catalytic and spectroscopic methods. Zinc-containing HZSM-5 zeolites and titanosilicalites with moderate Ti/Si ratios are shown to exhibit a better catalytic performance in NO decomposition as compared with conventionally used Cu/HZSM-5 zeolites and amorphous Cu-containing catalysts. Dehydroxylation of the HZSM-5 zeolite by calcination at 1120 K results in an enhancement of the NO conversion.