Synergistic impact of nano-supramolecular coordination polymer based on cadmium, ethyl nicotinate and thiocyanate ligands as efficient catalyst to remove harmful elements from wastewater.

Under ultrasonication, cadmium nitrate tetrahydrates, ethyl nicotinate (EN), and potassium thiocyanate as connecting ligand self-assembled to form the nanosized supramolecular coordination polymer (NSCP1) and the crystalline supramolecular coordination polymer (SCP1) [Cd(EN)(SCN)]. Single crystal SCP1 X-ray diffraction (XRD) revealed that Cd has an octahedral shape. The network structure of SCP1 is composed of chair conformation cyclic [Cd(SCN)] building blocks that form a one dimensional (1D) chain with bilaterally coordinated EN.

The impact of environmentally friendly supramolecular coordination polymers as carbon steel corrosion inhibitors in HCl solution: synthesis and characterization.

Two 3D-supramolecular coordination polymers (SCP1 & SCP2) have been synthesized and characterized by physicochemical and spectroscopic methods. In a solution of 1.0 M HCl, SCPs were used to prevent corrosion of carbon steel (CS).

Experimental and theoretical studies of the efficiency of metal-organic frameworks (MOFs) in preventing aluminum corrosion in hydrochloric acid solution.

Aluminum corrosion inhibitors "{[CuI (CN)(phen) CuII (CN)(phen)]5HO},(MOF1) and {[CuI(CN)(phen)CuII(CN)(phen)]5HO}@TiO (MOF1@TiO) were studied in one molar HCl solution". The ML results for three different temperatures (25-45 °C) were compared with the results of PDP and EIS analyses. The adsorption of inhibitors on Al surfaces has been calculated and discussed by a Langmuir isotherm.

Insights into the use of two novel supramolecular compounds as corrosion inhibitors for stainless steel in a chloride environment: experimental as well as theoretical investigation.

Novel supramolecular (SCPs) compounds such as: {[Ni (EIN)(NCS)]}, SCP1 and {[Co (EIN) (NCS)]}, SCP2 have been studied using weight loss (WL) and electrochemical tests on the corrosion performance of stainless steel 304 (SS304) in 1.0 M hydrochloric acid (HCl) solution. The experimental results revealed that inhibition efficacy (%) rises with increasing concentrations of SCPs and reached 92.

Experimental and computational approaches of methoxy naphthylbithiophene derivatives and their use as corrosion protection for carbon steel in acidic medium.

The inhibition efficiency and adsorption affinity were investigated for two novel compounds, namely: 6-methoxy-2-naphthyl-[2, 2'-bithiophene]-5-carboxamidine hydrochloride salt (MA-1440) and 5'-(4-chlorophenyl)-2, 2'-bifuran-5-carboxamidine hydrochloride salt (MA-1456). The inhibition study was conducted on carbon steel surface in 1.0 M HCl with different inhibitor doses and different temperature levels, to investigate the optimum dose and preferable temperature.