The effect of vine leaves processing techniques on Azoxystrobin, Fenazaquin, and Indoxacarb residues was investigated. Residue extraction following field application of pesticides and leaf processing was carried out using the QuEChERS method, with analysis conducted by LC-MS/MS. In dry conservation, Azoxystrobin's half-life was estimated to exceed a year, Fenazaquin's was 18 days, and Indoxacarb's was 142 days.
View Article and Find Full Text PDFTriazole fungicides are widely used to treat fungal pathogens in field crops, but very few studies have investigated whether fields of these crops constitute hotspots of azole resistance in . Soil samples were collected from 22 fields in two regions of eastern France and screened for triazole residues and azole-resistant (ARAf). Real-time quantitative PCR (qPCR) was used to quantify in these soil samples.
View Article and Find Full Text PDFDetention ponds (DPs) are used to reduce the pesticide inputs from runoff to surface water. This study aimed to assess the role of the sorption process in the mitigation of a DP made up of four successive units and built at the outlet of a vineyard catchment in Champagne (France) to treat runoff waters. Sorption kinetics and isotherms were studied for four pesticides with contrasting properties, cyazofamid (CYA), fludioxonil (FLX), fluopicolide (FLP) and oryzalin (ORY), in the presence of copper in sediments and four emergent macrophyte roots and rhizomes sampled in the DP units 2 (photodegradation) and 3 (phytoremediation).
View Article and Find Full Text PDFIn this study, imidacloprid, a systemic insecticide, currently having a specified European Commission MRL value for vine leaves (2 mg kg), was applied on a Lebanese vineyard under different commercial formulations: as a soluble liquid (SL) and water dispersible granules (WDG). In Lebanon, many commercial formulations of imidacloprid are subject to the same critical good agricultural practice (cGAP). It was, therefore, important to verify the variability in dissipation patterns according to matrix nature and formulation type.
View Article and Find Full Text PDFConstructed wetlands (CWs) are likely to reduce pesticide levels reaching surface water. However, the distribution of the water flow path between the main channel and isolated areas may influence global pesticide mitigation. Little information is known about the influence of water pathways on pesticide mitigation.
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