Pulsed-laser mode-mismatched crossed-beam thermal lens spectrometry within a small capillary tube: effect of flow rate and beam offset on the photothermal signal.

Pulsed-laser crossed-beam thermal lens spectrometry within a small capillary tube has been investigated using static as well as flowing samples. It is shown that when both the excitation and probe beams are perfectly aligned, time-resolved and peak signals are adequately described by the theoretical relations previously reported for infinite samples. Depending on flow velocity and/or the lateral offset between excitation and probe beam axis, the optical element formed by the excitation beam may have a diverging or converging effect on the probe beam.