Thermochemical Activity of Single- and Dual-Phase Oxide Compounds Based on Ceria, Ferrites, and Perovskites for Two-Step Synthetic Fuel Production.

This study focuses on the generation of solar thermochemical fuel (hydrogen, syngas) from CO and HO molecules via two-step thermochemical cycles involving intermediate oxygen-carrier redox materials. Different classes of redox-active compounds based on ferrite, fluorite, and perovskite oxide structures are investigated, including their synthesis and characterization associated with experimental performance assessment in two-step redox cycles. Their redox activity is investigated by focusing on their ability to perform the splitting of CO during thermochemical cycles while quantifying fuel yields, production rates, and performance stability.

A Review of Oxygen Carrier Materials and Related Thermochemical Redox Processes for Concentrating Solar Thermal Applications.

Redox materials have been investigated for various thermochemical processing applications including solar fuel production (hydrogen, syngas), ammonia synthesis, thermochemical energy storage, and air separation/oxygen pumping, while involving concentrated solar energy as the high-temperature process heat source for solid-gas reactions. Accordingly, these materials can be processed in two-step redox cycles for thermochemical fuel production from HO and CO splitting. In such cycles, the metal oxide is first thermally reduced when heated under concentrated solar energy.

Continuous solar-driven gasification of oil palm agricultural bio waste for high-quality syngas production.

Empty fruit bunch (EFB) from oil palm is a solid agricultural bio-waste obtained from the edible oil process. Continuous solar-driven gasification of EFB offers a bright carbon-neutral avenue to convert both EFB bio-waste and renewable solar energy into sustainable and clean syngas. High-temperature concentrated solar heat is used to provide the reaction enthalpy, and therefore biomass waste feedstock is entirely dedicated to produce hydrogen and carbon monoxide (syngas).

Robocasting of 3D printed and sintered ceria scaffold structures with hierarchical porosity for solar thermochemical fuel production from the splitting of CO.

We report the first ever robocast (additive manufacturing/3D printing) sintered ceria scaffolds, and explore their use for the production of renewable fuels solar thermochemical fuel production (STFP, water and carbon dioxide splitting using concentrated solar energy). CeO catalyst scaffolds were fabricated as 50 mm diameter discs (struts and voids ∼500 μm), sintered at 1450 °C, with specific surface area of 1.58 m g.

Immunometabolism Modulation in Therapy.

The study of cancer biology should be based around a comprehensive vision of the entire tumor ecosystem, considering the functional, bioenergetic and metabolic state of tumor cells and those of their microenvironment, and placing particular importance on immune system cells. Enhanced understanding of the molecular bases that give rise to alterations of pathways related to tumor development can open up new therapeutic intervention opportunities, such as metabolic regulation applied to immunotherapy. This review outlines the role of various oncometabolites and immunometabolites, such as TCA intermediates, in shaping pro/anti-inflammatory activity of immune cells such as MDSCs, T lymphocytes, TAMs and DCs in cancer.