Publications by authors named "Sıddık İcli"
Synthesis, characterization and optoelectronic properties of a new perylene diimide-benzimidazole type solar light harvesting dye.
Spectrochim Acta A Mol Biomol Spectrosc
July 2014
Article Synopsis
- A new small molecule, BI-PDI, was created through a chemical reaction involving specific precursors, which showed strong light absorption between 350 and 750 nm when formed into thin films.
- The energy levels of the BI-PDI dye, crucial for solar cell function, were found to be about -5.92 eV for the highest occupied molecular orbital (HOMO) and -3.82 eV for the lowest unoccupied molecular orbital (LUMO).
- When used in bulk heterojunction solar cells, BI-PDI demonstrated good external quantum efficiencies across the visible spectrum; however, its performance was hampered by issues like aggregation and poor charge mobility in the active layer.
Singlet oxygen quantum yields (ΦΔ) of different perylene diimides (PDIs) containing phenyl (PDI-Ph), pyrene (PDI-Pyr), and indole (PDI-In) units in bay positions of the ring were determined using 1,3-diphenylisobenzofuran (DPBF) method in toluene/methanol (99:1) system. Pyrene-substituted PDI were the most efficient singlet oxygen generator among the investigated photosensitizers with a quantum yield of Φ Δ = 0.93 in toluene/methanol.
View Article and Find Full Text PDFSahara desert sand (SaDeS) was employed as a mineral sorbent for retaining organic dyes from aqueous solutions. Natural sand has demonstrated a strong affinity for organic dyes but significantly lost its adsorption capacity when it was washed with water. Therefore, characterization of both natural and water washed sand was performed by XRD, BET, SEM and FTIR techniques.
View Article and Find Full Text PDFA novel distyryl-substituted boradiazaindacene (BODIPY) dye displays interesting properties as a sensitizer in DSSC systems, opening the way to further exploration of structure-efficiency correlation within this class of dyes.
View Article and Find Full Text PDFNew [Ru(L1)(dcbpy)(NCS)2] complex was synthesized in a one-pot reaction starting from [RuCl2(p-cymene)]2, where the ligands (dcbpy=4,4'-dicarboxy-2,2'-bipyridine, L1=dipyrido[3,2-a:2',3'-c]phenazine-11-ylcarbonyl)-sodium) are introduced sequentially. The resulting complex was characterized by IR, NMR, and elemental analysis. The complex was labeled with I-131.
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