Revisiting the Electrochemical Nitrogen Reduction on Molybdenum and Iron Carbides: Promising Catalysts or False Positives?

The electrochemical dinitrogen reduction reaction (NRR) has recently gained much interest as it can potentially produce ammonia from renewable intermittent electricity and replace the Haber-Bosch process. Previous literature studies report Fe- and Mo-carbides as promising electrocatalysts for the NRR with activities higher than other metals. However, recent understanding of extraneous ammonia and nitrogen oxide contaminations have challenged previously published results.

Thickness dependent terahertz emission from cobalt thin films.

When cobalt thin films are illuminated with femtosecond laser pulses, we observe the emission of terahertz pulses. For a cobalt film thickness less than about 40 nm, the THz electric field direction rotates when the sample is rotated about the surface normal. This azimuthal angle-dependent emission is consistent with the assumption that laser-induced changes in an in-plane magnetization are responsible for the emission.

Enhanced terahertz emission by coherent optical absorption in ultrathin semiconductor films on metals.

We report on the surprisingly strong, broadband emission of coherent terahertz pulses from ultrathin layers of semiconductors such as amorphous silicon, germanium and polycrystalline cuprous oxide deposited on gold, upon illumination with femtosecond laser pulses. The strength of the emission is surprising because the materials are considered to be bad (amorphous silicon and polycrystalline cuprous oxide) or fair (amorphous germanium) terahertz emitters at best. We show that the strength of the emission is partly explained by cavity-enhanced optical absorption.