A new paper-based analytical device design was fabricated by a wax printing method for simultaneous determination of Cu(ii), Co(ii), Ni(ii), Hg(ii), and Mn(ii). Colorimetry was used to quantify these heavy metal ions using bathocuproine (Bc), dimethylglyoxime (DMG), dithizone (DTZ), and 4-(2-pyridylazo) resorcinol (PAR) as complexing agents. The affinity of complexing agents to heavy metal ions is dependent on the formation constant (K).
View Article and Find Full Text PDFBackground: Citrus greening disease (Huanglongbing, HLB) has infected >90% of Florida's oranges and thus growers are desperate to improve pest management strategies. In this field study, insecticide application efficacy was investigated with liquid chromatography mass spectrometry to determine if insecticide concentration and distribution were effective at killing the target pest Asian citrus psyllids (ACP). Sample discs attached to leaves were sprayed with imidacloprid and malathion at a field site in Florida.
View Article and Find Full Text PDFCapillary forces are commonly employed to transport fluids in pump-free microfluidic platforms such as paper-based microfluidics. However, since paper is a porous material consisting of nonuniform cellulose fibers, it has some limitations in performing stable flow functions like mixing. Here, we developed a pump-free microfluidic device that enables rapid mixing by combining paper and plastic.
View Article and Find Full Text PDFThis article reports the first fluorescent distance-based paper device coupled with an evaporating preconcentration system for determining trace mercury ions (Hg) in water. The fluorescent nitrogen-doped carbon dots (NCDs) were synthesized by a one-step microwave method using citric acid and ethylenediamine. The fluorescence turn-off of the NCDs in the presence of Hg was visualized with a common black light, and the distance of the quenched fluorescence correlated to Hg concentration.
View Article and Find Full Text PDF