Correction for 'π-Facial selectivity in the Diels-Alder reaction of glucosamine-based chiral furans and maleimides' by Cornelis H. M. van der Loo , , 2023, , 1888-1894, https://doi.
View Article and Find Full Text PDFFurans derived from carbohydrate feedstocks are a versatile class of bio-renewable building blocks and have been used extensively to access 7-oxanorbornenes Diels-Alder reactions. Due to their substitution patterns these furans typically have two different π-faces and therefore furnish racemates in [4 + 2]-cycloadditions. We report the use of an enantiopure glucosamine derived furan that under kinetic conditions predominantly affords the -product with a high π-face selectivity of .
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