Plasma-Catalyst Dynamics: Nonthermal Activation of Strong Metal-Support Interactions.

Nonthermal plasma-surface interactions enable transformative advancements in green chemistry, healthcare, materials processing, pollution abatement, and the ever-growing area of plasma catalysis. In the context of plasma catalysis, the fate of the active sites during plasma treatment has remained enigmatic, and observation of low-temperature plasma-catalyst events has been challenging. The induction of strong metal-support interactions (SMSI) through high-temperature hydrogen treatment is a well-documented and established, yet limited, method to impact selectivity and stability of noble metal catalysts on reducible supports.

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Plasma-surface coupling has emerged as a promising approach to perform chemical transformations under mild conditions that are otherwise difficult or impossible thermally. However, a few examples of inexpensive and accessible / techniques exist for observing plasma-solid interactions, which has prevented a thorough understanding of underlying surface mechanisms. Here, we provide a simple and adaptable design for a dielectric barrier discharge (DBD) plasma cell capable of interfacing with Fourier transform infrared spectroscopy (FTIR), optical emission spectroscopy (OES), and mass spectrometry (MS) to simultaneously characterize the surface, the plasma phase, and the gas phase, respectively.