Vanadium O-Centered Selenoiodide Complex: Synthesis and Structure of VO(Se)I·I.

The first vanadium selenoiodide VO(Se)I·I was synthesized at a moderate temperature of 220 °C from V, Se, I, and water. Its crystal structure (tetragonal space group 4/, = 11.838(1) Å, = 18.