Due to the growing concerns about pharmaceutical contamination and its devastating impact on the economy and the health of humans and the environment, developing efficient approaches for removing such contaminants has become essential. Adsorption is a cost-effective technique for removing pollutants. Thus, in this work, banana peels as agro-industrial waste were utilized for synthesizing activated carbon for removing pharmaceuticals, namely amoxicillin and carbamazepine from different water matrices.
View Article and Find Full Text PDFThis study endeavors to develop cost-effective environmentally friendly technology for removing harmful residual pharmaceuticals from water and wastewater by utilizing the effective adsorption of pistachio shell (PS) biochar and the degradation potency of laccase immobilized on the biochar (L@PSAC). The carbonatization and activation of the shells were optimized regarding temperature, time, and NHNO/PS ratio. This step yielded an optimum PS biochar (PSAC) with the highest porosity and surface area treated at 700 °C for 3 h using an NHNO/PS ratio of 3% wt.
View Article and Find Full Text PDFThe olive stone is a large waste product of the olive oil extraction industry. The present study investigates developing activated carbon from olive stone waste (OSAC) to remove pharmaceuticals from water. Different temperatures and olive stone: KOH ratios were studied.
View Article and Find Full Text PDFThis study examined the use of modified multiwall carbon nanotubes (M-MWCNTs) with immobilized laccase (L@M-MWCNTs) for removing ciprofloxacin (Cip), carbamazepine (Cbz), diclofenac (Dcf), benzo[a]pyrene (Bap), and anthracene (Ant) from different water samples. The synthesized materials were characterized using an array of advanced analytical techniques. The physical immobilization of laccase onto M-MWCNTs was confirmed through Scanning electron microscope (SEM)-dispersive X-ray spectroscopy (EDS) analysis and Brunner-Emmet-Teller (BET) surface area measurements.
View Article and Find Full Text PDFIn this study, pomegranate peels (PPs) as an abundant fruit processing waste was used to produce cost-effective, eco-friendly, and high-quality activated carbon. The produced carbon (fossil free activated carbon) was used for immobilizing laccase to remove a range of emerging pollutants namely diclofenac, amoxicillin, carbamazepine, and ciprofloxacin from water and wastewater. The loaded activated carbon by laccase (LMPPs) and the unloaded one (MPPs) were characterized using advanced surface chemistry analysis techniques.
View Article and Find Full Text PDFRecent Iraqi battles against ISIS in 2014 and 2015 resulted in the destruction or severe damage to several refineries' infrastructure. This, along with other factors, has led to the release and accumulation of a wide range of hazardous chemicals into the environment, for instance, polycyclic aromatic hydrocarbons (PAH). Thus, for the first time, a comprehensive 16 PAHs measurements campaign over the course of six months near the oil refineries along the Tigris River and its estuaries was investigated.
View Article and Find Full Text PDFThe current study deals with the biological response variations on some biochemical properties of the freshwater green algae by exposure to different Mg concentrations (5, 10, and 15) mg/L. Physiological and biochemical parameters, including growth curve, doubling time, photosynthesis pigments, total protein and carbohydrates were investigated. Moreover, enzymatic parameters such as catalase (CAT), superoxide dismutase (SOD), and reactive oxygen species (ROS) were also examined.
View Article and Find Full Text PDFThis study presented for the first time a comprehensive measurement campaign of 16 PAHs along the Euphrates River for five months, in both water and sediment samples. Our study revealed that the PAHs contamination increased along the flow direction due to the increasing non-point pollution and the return flows of agriculture. The 5-6 rings PAHs were dominant in water and sediment samples with an average of 42 % and 50 %, respectively.
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