Retention and release of black phosphorus nanoparticles in porous media under various physicochemical conditions.

Black phosphorus nanosheets/nanoparticles (BPNs) are widely applied in many fields. However, the transport of BPNs in the subsurface still has not yet been reported and there is increasing concern about potential adverse impacts on ecosystems. Roles of median grain size and surface roughness, BPN concentration, and solution chemistries (pH, ionic strength, and cation types) on the retention and release of BPNs in column experiments were therefore investigated.

Facilitated transport of microplastics and nonylphenol in porous media with variations in physicochemical heterogeneity.

Nonylphenol (Noph) has garnered worldwide concern as a typical endocrine disruptor due to its toxicity, estrogenic properties, and widespread contamination. To better elucidate the interaction of Noph with ubiquitously existing microplastics (MPs) and the potential interdependence of their transport behaviors, batch adsorption and column experiments were conducted, paired with mathematical modeling. Compared with sand, MPs and soil colloids show stronger adsorption affinity for Noph due to the formation of hydrogen bonding and the larger numbers of interaction sites that are available on solid surfaces.