Preparation and evaluation of FeO@C@NiCo-LDH@CDs composites for magnetic solid-phase extraction of trace endocrine disruptors.

The widespread use of endocrine disruptors (EDPs) has certain potential hazards to organisms and environments, and it is particularly important to develop effective pretreatment methods before detection of EDPs in complex samples. In this work, a novel magnetic nanocomposite decorated with layered double hydroxides (LDHs) and carbon dots (CDs) was designed and prepared for magnetic solid-phase extraction (MSPE) of EDPs (bisphenol S, bisphenol F, bisphenol A, bisphenol AF, diethylstilbestrol and 4-cumylphenol) combined with high-performance liquid chromatography-ultraviolet (HPLC-UV) detection. The prepared composites were characterized by field emission scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS), and the adsorption mechanism towards these EDPs might be mainly based on hydrogen bonds and π-π conjugation.

Three-dimensional flower-like SnS materials for dispersive solid-phase extraction of endocrine-disrupting phenols.

In this study, three-dimensional flower-like tin disulfide materials were prepared, and a highly efficient dispersive solid-phase extraction method was developed using the obtained three-dimensional tin disulfide adsorbents for the preconcentration and determination of six endocrine-disrupting phenols in combination with high-performance liquid chromatography-ultraviolet detection. Several important experimental parameters influencing extraction efficiency were investigated, including the amount of adsorbent, ultrasound time, sample solution pH, sample volume, type of elution solvent, desorption time, and the number of desorption times. Under the optimized experimental conditions, the developed method showed good linearity with the determination coefficients of 0.

[Effect of tea polyphenols on proliferation of human periodontal ligament fibroblasts].

Objective: To determine the effect of tea polyphenol (TP) on the proliferation of human periodontal ligament fibroblasts (HPDLFs).

Methods: HPDLFs were primary cultured from tissue explants, and the cells of the 5th to 8th passages were used after immunohistochemical identification (with SABC method) of keratin and vimentin expressions. The cells were divided into 5 groups and treated with TP at 1, 0.