Polymer-Ion Interaction Prompted Quasi-Solid Electrolyte for Room-Temperature High-Performance Lithium-Ion Batteries.

Lithium-ion batteries using quasi-solid gel electrolytes (QSEs) have gained increasing interest due to their enhanced safety features. However, their commercial viability is hindered by low ionic conductivity and poor solid-solid contact interfaces. In this study, a QSE synthesized by in situ polymerizing methyl methacrylate (MMA) in 1,2-dimethoxyethane (DME)-based electrolyte is introduced, which exhibits remarkable performance in high-loading graphite||LiNiCoMnO (NCM811) pouch cells.

Insight into Multiple Intermolecular Coordination of Composite Solid Electrolytes via Cryo-Electron Microscopy for High-Voltage All-Solid-State Lithium Metal Batteries.

Polymer/ceramic-based composite solid electrolytes (CSE) are promising candidates for all-solid-state lithium metal batteries (SLBs), benefiting from the combined mechanical robustness of polymeric electrolytes and the high ionic conductivity of ceramic electrolytes. However, the interfacial instability and poorly understood interphases of CSE hinder their application in high-voltage SLBs. Herein, a simple but effective CSE that stabilizes high-voltage SLBs by forming multiple intermolecular coordination interactions between polyester and ceramic electrolytes is discovered.

Biobased Self-Growing Approach toward Tailored, Integrated High-Performance Flexible Lithium-Ion Battery.

Here we present an innovative, universal, scalable, and straightforward strategy for cultivating a resilient, flexible lithium-ion battery (LIB) based on the bacterial-based self-growing approach. The electrodes and separator layers are integrated intrinsically into one unity of sandwich bacterial cellulose integrated film (SBCIF), with various active material combinations and tailored mechanical properties. The flexible LIB thereof showcases prominent deformation tolerance and multistage foldability due to the unique self-generated wavy-like structure.

Stable Lithium Metal Anodes with a GaO Artificial Solid Electrolyte Interphase in Damp Air.

As a promising high energy density electrode material for rechargeable batteries, lithium (Li) metal is still suffering from air/water instability due to its highly reactive nature. In addition, the Li dendrite issue in Li metal batteries needs to be resolved to ensure the safety of batteries and for wide applications. Herein, we demonstrate that a simple compact GaO layer formed using liquid metal (LM) can act as an artificial solid electrolyte interphase to block moisture and oxygen in the air from corroding the lithium metal.