Anaerobic biodegradation enables zero liquid discharge of two-stage nanofiltration system for microelectronic wastewater treatment.

Nanofiltration (NF) is a promising technology in the treatment of microelectronic wastewater. However, the treatment of concentrate derived from NF system remains a substantial technical challenge, impeding the achievement of the zero liquid discharge (ZLD) goal in microelectronic wastewater industries. Herein, a ZLD system, coupling a two-stage NF technology with anaerobic biotechnology was proposed for the treatment of tetramethylammonium hydroxide (TMAH)-contained microelectronic wastewater.

Trade-off between Endocrine-Disrupting Compound Removal and Water Permeance of the Polyamide Nanofiltration Membrane: Phenomenon and Molecular Insights.

The polyamide (PA) nanofiltration (NF) membrane has the potential to remove endocrine-disrupting compounds (EDCs) from water and wastewater to prevent risks to both the aquatic ecosystem and human health. However, our understanding of the EDC removal-water permeance trade-off by the PA NF membrane is still limited, although the salt selectivity-water permeance trade-off has been well illustrated. This constrains the precise design of a high-performance membrane for removing EDCs.

Understanding Rejection Mechanisms of Trace Organic Contaminants by Polyamide Membranes via Data-Knowledge Codriven Machine Learning.

Data-driven machine learning (ML) provides a promising approach to understanding and predicting the rejection of trace organic contaminants (TrOCs) by polyamide (PA). However, various confounding variables, coupled with data scarcity, restrict the direct application of data-driven ML. In this study, we developed a data-knowledge codriven ML model via domain-knowledge embedding and explored its application in comprehending TrOC rejection by PA membranes.

A review on artificial water channels incorporated polyamide membranes for water purification: Transport mechanisms and performance.

While thin-film composite (TFC) polyamide (PA) membranes are advanced for removing salts and trace organic contaminants (TrOCs) from water, TFC PA membranes encounter a water permeance-selectivity trade-off due to PA layer structural characteristics. Drawing inspiration from the excellent water permeance and solute rejection of natural biological channels, the development of analogous artificial water channels (AWCs) in TFC PA membranes (abbreviated as AWCM) promises to achieve superior mass transfer efficiency, enabling breaking the upper bound of water permeance and selectivity. Herein, we first discussed the types and structural characteristics of AWCs, followed by summarizing the methods for constructing AWCM.

Anaerobic hydrolysis of recalcitrant tetramethylammonium from semiconductor wastewater: Performance and mechanisms.

The treatment of tetramethylammonium hydroxide (TMAH)-bearing wastewater, generated in the electronic and semiconductor industries, raises significant concerns due to the neurotoxic, recalcitrant, and bio-inhibiting effects of TMAH. In this study, we proposed the use of an anaerobic hydrolysis bioreactor (AHBR) for TMAH removal, achieving a high removal efficiency of approximately 85%, which greatly surpassed the performance of widely-used advanced oxidation processes (AOPs). Density functional theory calculations indicated that the unexpectedly poor efficiency (5.

Metal-Organic Framework with a Redox-Active Bridge Enables Electrochemically Highly Selective Removal of Arsenic from Water.

Selective removal of trace, highly toxic arsenic from water is vital to ensure an adequate and safe drinking water supply for over 230 million people around the globe affected by arsenic contamination. Here, we developed an Fe-based metal-organic framework (MOF) with a ferrocene (Fc) redox-active bridge (termed Fe-MIL-88B-Fc) for the highly selective removal of As(III) from water. At a cell voltage of 1.

Enhancing Stability of Tannic Acid-Fe Nanofiltration Membrane for Water Treatment: Intercoordination by Metal-Organic Framework.

Tannic acid (TA)-Fe nanofiltration (NF) membrane has been demonstrated to possess more favorable removal of trace organic contaminants (TrOCs) over the conventional polyamide NF membrane. However, the drawback of acid instability severely hinders the practical application of TA-Fe NF membrane in the treatment of (weak) acidic wastewater containing TrOCs (e.g.

Membrane fouling behaviors in a full-scale zero liquid discharge system for cold-rolling wastewater brine treatment: A comprehensive analysis on multiple membrane processes.

The challenge of water scarcity drives zero liquid discharge (ZLD) treatment to maximize reuse of industrial wastewater. Deciphering the characteristics and mechanisms of membrane fouling in the membrane-based ZLD system is crucial for the development of effective fouling control strategies. However, current studies only focused on the membrane fouling of single step, lacking in-depth understanding on the ZLD systems using multiple membrane processes.

Removal of -toluenesulfonic acid from wastewater using a filtration-enhanced electro-Fenton reactor.

Rapid global industrialization accompanies the discharge of industrial wastewater. -Toluenesulfonic acid (PTSA), a kind of aromatic sulfonate that belongs to the refractory organic pollutant, is one of the most widely used chemicals in pharmaceutical, dye, petrochemical and plastic industries. In this study, we developed a filtration-enhanced electro-Fenton (FEEF) reactor to remove PTSA from synthetic wastewater.

Roles of Anion-Cation Coupling Transport and Dehydration-Induced Ion-Membrane Interaction in Precise Separation of Ions by Nanofiltration Membranes.

Nanofiltration (NF) membranes are playing increasingly crucial roles in addressing emerging environmental challenges by precise separation, yet understanding of the selective transport mechanism is still limited. In this work, the underlying mechanisms governing precise selectivity of the polyamide NF membrane were elucidated using a series of monovalent cations with minor hydrated radius difference. The observed selectivity of a single cation was neither correlated with the hydrated radius nor hydration energy, which could not be explained by the widely accepted NF model or ion dehydration theory.

Efficient removal of neonicotinoid by singlet oxygen dominated MoS/ceramic membrane-integrated Fenton-like process.

Removal of neonicotinoids (NEOs) from contaminated water is of great importance for both ecological environment and human health. However, conventional Fenton process might be insufficient for NEOs removal due to short lifetime for generated HO and limited Fe/Fe redox cycle. Advancing Fenton process to produce singlet oxygen can be an effective route to improve its efficacy for NEOs removal.

Green Solvent Cleaning Removes Irrecoverable Foulants from End-of-Life Membranes in Membrane Bioreactors: Efficacy and Mechanisms.

Removal of irrecoverable foulants, which cannot be removed by conventional chemical cleaning, from end-of-life (EOL) membranes remains a substantial challenge due to the strong interaction between the foulants and membrane matrix. Herein, we developed a green solvent cleaning strategy based on Hansen solubility parameters to achieve the removal of irrecoverable foulants from the EOL polyvinylidene fluoride (PVDF) membranes serving for 6 years in a large-scale membrane bioreactor (MBR). We selected methyl-5-(dimethylamino)-2-methyl-5-oxopentanoate (MDMO) as the green solvent due to its strong interaction with the PVDF material, which might enable the substitution of binding sites of irrecoverable foulants.

Recent advances in electrocatalytic membrane for the removal of micropollutants from water and wastewater.

The increasing occurrence of micropollutants in water and wastewater threatens human health and ecological security. Electrocatalytic membrane (EM), a new hybrid water treatment platform that integrates membrane separation with electrochemical technologies, has attracted extensive attention in the removal of micropollutants from water and wastewater in the past decade. Here, we systematically review the recent advances of EM for micropollutant removal from water and wastewater.

Biofouling suppresses effluent toxicity in an electrochemical filtration system for remediation of sulfanilic acid-contaminated water.

Electrochemical filtration system (EFS) has received broad interest due to its high efficiency for organic contaminants removal. However, the porous nature of electrodes and flow-through operation mode make it susceptible to potential fouling. In this work, we systematically investigated the impacts of biofouling on sulfanilic acid (SA) removal and effluent toxicity in an EFS.

Modification of ultrafiltration membrane with antibacterial agent intercalated layered nanosheets: Toward superior antibiofouling performance for water treatment.

Membrane fouling, especially biofouling induced by biofilm formation on membranes, can result in frequent cleaning or even replacement of membranes. Fabrication of membrane with excellent antibiofouling property is quite attractive due to its effectiveness and low-impact on the operation of membrane-based process. Herein, a cationic antibacterial agent, quaternary ammonium compound (QAC), was intercalated into the interlayer spaces of the MgAl layered double hydroxide (QAC/LDH) by self-assembly.

Artificial intelligence-incorporated membrane fouling prediction for membrane-based processes in the past 20 years: A critical review.

Membrane fouling is one of major obstacles in the application of membrane technologies. Accurately predicting or simulating membrane fouling behaviours is of great significance to elucidate the fouling mechanisms and develop effective measures to control fouling. Although mechanistic/mathematical models have been widely used for predicting membrane fouling, they still suffer from low accuracy and poor sensitivity.

Metal-organic framework enables ultraselective polyamide membrane for desalination and water reuse.

While reverse osmosis (RO) is the leading technology to address the global challenge of water scarcity through desalination and potable reuse of wastewater, current RO membranes fall short in rejecting certain harmful constituents from seawater (e.g., boron) and wastewater [e.

Self-Enhanced Decomplexation of Cu-Organic Complexes and Cu Recovery from Wastewaters Using an Electrochemical Membrane Filtration System.

Heavy metals in industrial wastewaters are typically present as stable metal-organic complexes with their cost-effective treatment remaining a significant challenge. Herein, a self-enhanced decomplexation scenario is developed using an electrochemical membrane filtration (EMF) system for efficient decomplexation and Cu recovery. Using Cu-EDTA as a model pollutant, the EMF system achieved 81.

An electrochemical membrane biofilm reactor for removing sulfonamides from wastewater and suppressing antibiotic resistance development: Performance and mechanisms.

Sulfonamides, such as sulfadiazine (SDZ), are frequently detected in water and wastewater with their toxic and persistent nature arousing much concern. In this work, a novel electrochemical membrane biofilm reactor (EMBfR) was constructed for the removal of SDZ whilst suppressing the development of antibiotic resistance genes (ARGs). Results showed that the EMBfR achieved 94.

Constructing interlayer to tailor structure and performance of thin-film composite polyamide membranes: A review.

Thin-film composite (TFC) structured membranes based on polyamide (PA) chemistry is the gold standard of nanofiltration and reverse osmosis-based technologies for water purification and desalination. Constructing interlayer between porous substrate and PA layer is a promising strategy to address the ubiquitous trade-off between permeability and selectivity, which is typically encountered by conventional TFC PA membranes. The progress in the interlayer benefits the precise control of interfacial polymerization process, which therefore can tailor the structure and performance of advanced TFC PA membranes.

Fabrication of High-Performance Thin-Film Composite Nanofiltration Membrane by Dynamic Calcium-Carboxyl Intra-Bridging during Post-Treatment.

Widespread applications of nanofiltration (NF) and reverse osmosis (RO)-based processes for water purification and desalination call for high-performance thin-film composite (TFC) membranes. In this work, a novel and facile modification method was proposed to fabricate high-performance thin-film composite nanofiltration membrane by introducing Ca in the heat post-treatment. The introduction of Ca induced in situ Ca-carboxyl intra-bridging, leading to the embedment of Ca in the polyamide (PA) layer.

Dually Charged MOF-Based Thin-Film Nanocomposite Nanofiltration Membrane for Enhanced Removal of Charged Pharmaceutically Active Compounds.

Removal of pharmaceutically active compounds (PhACs) is of great importance in wastewater reclamation due to their potent negative impacts on human health. Typical polyamide nanofiltration (NF) membranes are negatively charged, which compromises their rejection rate of positively charged PhACs. Herein, we propose to rationally design a novel thin-film nanocomposite (TFN) NF membrane featuring a dually charged metal organic framework (MOF) to effectively remove both positively and negatively charged PhACs.

Recent advances in Cu-Fenton systems for the treatment of industrial wastewaters: Role of Cu complexes and Cu composites.

Cu-based Fenton systems have been recognized as a promising suite of technologies for the treatment of industrial wastewaters due to their high catalytic oxidation capacity. Rapid progress regarding Cu Fenton systems has been made not only in fundamental mechanistic aspects of these systems but also with regard to applications over the past decade. Based on available literature, this review synthesizes the recent advances regarding both the understanding and applications of Cu-based Fenton processes for industrial wastewater treatment.

Hydrophilic Selective Nanochannels Created by Metal Organic Frameworks in Nanofiltration Membranes Enhance Rejection of Hydrophobic Endocrine-Disrupting Compounds.

Rejection of endocrine-disrupting compounds (EDCs) by thin-film composite (TFC) polyamide membranes remains a challenging issue in wastewater reclamation applications because of the unfavorable hydrophobic interaction between EDCs and membranes. Herein, we investigated the incorporation of hydrophilic metal organic frameworks (MOFs) into the polyamide layer to create water/EDC selective nanochannels for enhancing EDC rejection. Using MIL-101(Cr) MOF as a nanofiller, the water flux of the MOF0.