Ambipolar Self-Host Functionalization Accelerates Blue Multi-Resonance Thermally Activated Delayed Fluorescence with Internal Quantum Efficiency of 100.

Emerging multi-resonance (MR) thermally activated delayed fluorescence (TADF) emitters can combine 100% exciton harvesting and high color purity for their organic light-emitting diodes (OLED). However, the highly planar configurations of MR molecules lead to intermolecular-interaction-induced quenching. A feasible way is integrating host segments into MR molecules, namely a "self-host" strategy, but without involving additional charge transfer and/or vibrational components to excited states.