Solvent-annealing-induced self-organization of poly(3-hexylthiophene), a high-performance electrochromic material.

We have systematically studied the self-organization of poly(3-hexylthiophene) (P3HT), an electrochromic material, upon control of the solvent evaporation rate. We characterized these polymer films using atomic force microscopy and X-ray diffraction measurements. Well-ordered P3HT structures were developed after solvent annealing; these highly crystalline structures exhibited enhanced electrochromic contrast and reduced resistance within the film, leading to larger coloration efficiencies and faster switching times.

First stable reduced form of [Co(5)](+10): fine tuning of linear pentacobalt(ii) complexes containing delocalized metal-metal bonds through ligand modification.

Pentacobalt EMACs [Co(5)(mu(5)-dpzpda)(4)X(2)] (X = Cl(-) (), NCS(-) ()) with fine-tuning of the supporting ligand based on the tripyridyldiamine ligand, N,N'-di(pyrazin-2-yl)pyridine-2,6-diamine (H(2)dpzpda), and their reduced form (Ph(4)P)[Co(5)(mu(5)-dpzpda)(4)X(2)] (X = Cl(-) (), NCS(-) ()) were first synthesized and structurally characterized. The structures of showed direct Co-Co bonds with Co-Co distances in the range 2.2385(7)-2.

New versatile ligand family, pyrazine-modulated oligo-alpha-pyridylamino ligands, from coordination polymer to extended metal atom chains.

Here we designed and synthesized a new ligand, di(2-pyrazyl)amine (Hdpza) (1) and studied its coordination modes and the corresponding complexes with Cu(II), Co(II), Ni(II) and Cr(II). Hdpza is an analogue of the well-studied di(2-pyridyl)amine (Hdpa) ligand, which was used to generate the first extended metal atom chain. Three types of coordination modes were found: anti-anti style which resulted in a mononuclear compound [Cu(Hdpza)(2)(H(2)O)(2)](ClO(4))(2) (2); anti-syn which was observed in a complex for the first time and resulted in a 2-D coordination polymer [Co(mu(2)-Hdpza)(2)(NCS)(2)] (3); and syn-syn type which was observed in extended metal atom chains [Ni(3)(mu(3)-dpza)(4)Cl(2)] (4), [Ni(3)(mu(3)-dpza)(4)(NCS)(2)] (5) and [Cr(3)(mu(3)-dpza)(4)Cl(2)] (6).

Four quadruple metal-metal bonds lined up: linear nonachromium(II) metal string complexes.

Through a new pyrazine-modulated penta-pyridyl-tetraamine ligand, H(4)N(9)-mpz, linear nonachromium(II) complexes with four quadruple metal-metal bonds were successfully obtained, and their structure, magnetic and electrochemistry properties were studied.