Electrocatalytic oxidation of pyrrole on a quasi-reversible silver nanodumbbell particle surface for supramolecular porphyrin production.

Photoactive supramolecular porphyrin assemblies are attractive molecules for light-harvesting applications. This is due to their relatively non-toxicity, biological activities and charge and energy exchange characteristics. However, the extreme cost associated with their synthesis and requirements for toxic organic solvents during purification pose a challenge to the sustainability characteristics of their applications.

Titanium dioxide and graphitic carbon nitride-based nanocomposites and nanofibres for the degradation of organic pollutants in water: a review.

The paper reviews graphitic carbon nitride-based nanostructured photocatalytic materials and nanofibres for applications in water purification. Titanium dioxide has shown unique features that continue to attract research and development (R&D) due to its unique properties such as availability, ultraviolet absorptivity, photocatalysis, adsorption of pollutants and solar cell engineering. Graphitic carbon nitride is an attractive photocatalyst due to its non-toxicity characteristics, good visible light absorption and good thermal and chemical stabilities.