Cellulose nanocrystals (CNCs) are a green resource which can produce photonic crystal films with structural colors in evaporation-induced self-assembly; CNC photonic crystal films present unique structural colors that cannot be matched by other colored materials. Recently, the mechanisms of CNC photonic crystal films with a unique liquid crystal structure were investigated to obtain homogenous, stable, and even flexible films at a large scale. To clarify the mechanism of colorful CNC photonic crystal films, we briefly summarize the recent advances from the correlations among the preparation methods, microstructures, and color properties.
View Article and Find Full Text PDFHydrogel-based flexible electronic devices have great potential in human motion monitoring, electronic skins, and human-computer interaction applications; hence, the efficient preparation of highly sensitive hydrogel-based flexible sensors is important. In the present work, the ultrafast polymerization of a hydrogel (1-3 min) was achieved by constructing a tannic acid (TA)-Fe dynamic redox system, which endowed the hydrogel with good adhesion performance (the adhesion strength in wood was 17.646 kPa).
View Article and Find Full Text PDFThe development of low-cost and high-performance flexible sensor materials is crucial for the advancement of wearable electronic devices, medical monitoring, and human-machine interfaces. In this study, a poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)-coated multiwalled carbon nanotube (MWCNT)-reinforced polydimethylsiloxane (PDMS) composite foam with a uniform organic/inorganic and inner/outer cooperative conductive network was developed to detect tensile and compressive forces. The study demonstrates that the internally cross-linked MWCNTs and PEDOT:PSS coatings within the foam framework play a crucial role in the porous structure and sensing properties of the composite foam.
View Article and Find Full Text PDFThe combination of organic and inorganic materials has been considered an effective solution for achieving ambient thermoelectric energy harvesting and has been developing rapidly. Here, PEDOT:PSS/MWCNT (PPM) composite hydrogels were synthesized using the self-assembled gelation process of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) and the interaction between PEDOT:PSS and multi-walled carbon nanotubes (MWCNTs) without the addition of any surfactant. After immersion in dimethyl sulfoxide and freeze-drying, the hydrogel is easily dispersed in water and used as a direct ink writing (DIW) 3D printing ink.
View Article and Find Full Text PDFIn this paper, a method for preparing a high-stability superhydrophobic paper with temperature-induced wettability transition is proposed. First, a temperature-responsive superhydrophobic triblock polymer PHFMA-PTSPM-PNIPAAm was prepared by one-step polymerization of TSPM, HFMA, and NIPAAm in a mass ratio of 0.3:0.
View Article and Find Full Text PDFThe oily wastewater generated in the industrial field is adversely affecting the environment, while the current methods for oil-water separation are complex and costly. Therefore, it is significant to use low cost and environmentally friendly materials to prepare a smart responsive superhydrophobic coating for the effective separation of oil-water mixtures. In this paper, a fluorine-free copolymer with pH responsiveness was fabricated by a solution impregnation method, and it was compounded by silica nanoparticles/polydimethylsiloxane to prepare a superhydrophobic coating on the paper and cotton fabric.
View Article and Find Full Text PDFSolid polymer electrolyte (SPE) is an important part of printed electrochemical gas sensors and are of value to electrochemical sensors. Here, a new type of SPE was prepared by dissolving a poly-vinylidene fluoride (PVDF) matrix in a 1-methyl-2-pyrrolidone (NMP) to immobilize 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM] [BF]), which was then used in a new electrochemical amperometric nitrogen dioxide sensor. The SPE was coated on a single electrode and attached to the electrode to construct a simple two-layer structure.
View Article and Find Full Text PDF