Construction of flexible porous 3D biochar based on electrospun rice straw-derived cellulose acetate with excellent adsorption properties toward organic pollutants.

Cellulose was extracted from rice straw waste by the intergrated technique of CHOH/HO, dilute alkali treatment and HO bleaching process, and rice straw-derived cellulose acetate was obtained by the acetylation reaction of cellulose. Flexible porous 3D biochars were constructed by the electrospinning, NaBH foaming and calcination process. Effects of calcination temperature, adsorption time, pH, pollutant concentration, interfering anions, and cycle times on the adsorption performance of 3D biochar were systematically investigated.

Correction: Guan et al. The Impurity Removal and Comprehensive Utilization of Phosphogypsum: A Review. 2024, , 2067.

In the original publication [...

Facile electrospinning-electrospray method to fabricate flexible rice straw-derived cellulose acetate/TiO nanofibrous membrane with excellent photocatalytic performance.

A novel and facile electrospinning-electrospray (EE) method that based on electrospinning technique and simultaneous electrospray was proposed to anchor TiO (P25) nanoparticles on the surface of rice straw-derived cellulose acetate (CA) nanofiber, a series of EE-CA/P25 nanofibrous membranes with different P25 dosage were successfully fabricated, which were characterized in terms of SEM, TEM, FI-IR, XRD, DRS, PL, UV-vis and 3D-EMMs, etc. Results confirmed that P25 nanoparticles were anchored on the surface of CA nanofiber. For different organic dyes of Methylene blue (MB), Rhodamine B (RhB) and Methyl orange (MO), EE-CA/P25 nanofibrous membrane toward MB dye showed the best photocatalytic degradation efficiency of 99.

The Impurity Removal and Comprehensive Utilization of Phosphogypsum: A Review.

Phosphogypsum (PG), a byproduct during the phosphoric acid production process, also known as the wet process, contains complex and diverse impurities, resulting in low utilization and considerable accumulation. This leads to a massive waste of land resources and a series of environmental pollution problems. Given the current urgent ecological and environmental situation, developing impurity removal processes with low energy consumption and high efficiency, exploring valuable resource recovery, preparing high value-added PG products, and broadening the comprehensive utilization ways of PG are significant strategies to promote the sustainable consumption of PG and sustainable development of the phosphorus chemical industry.

A Critical Review of the Enhanced Recovery of Rare Earth Elements from Phosphogypsum.

The increasing demand for rare earth elements (REEs), especially from new and innovative technology, has strained their supply, which makes the exploration of new REE sources necessary, for example, the recovery of REEs from phsophogypsum (PG). PG is a byproduct during the wet production of phosphoric acid, which is an attractive secondary resource for REEs due to a large amount of REEs locked in them. In most cases, REEs contained in PG are mainly encapsulated in the gypsum crystal, leading to a low leaching efficiency.

Ar plasma assists in enhanced oxygen evolution kinetics of MOG-derived multicomponent transition metal sulfides.

Transition metal sulfides are low-cost oxygen evolution reaction (OER) electrocatalysts that can potentially substitute noble metal catalysts. However, the adsorption process of their OER is impeded by their intrinsic poor catalytic activity. Constructing heterojunction and vacancy defects in transition metal sulfides is an efficient method to promote the process of oxygen evolution.

Rational design of dense microporous carbon derived from coal tar pitch towards high mass loading supercapacitors.

The compact carbon materials with huge specific surface area (SSA) and proper pore structure are highly desirable towards high-performance supercapacitors at the cell level. However, to well balance of porosity and density is still an on-going task. Herein, a universal and facile strategy of pre-oxidation-carbonization-activation is employed to prepare the dense microporous carbons from coal tar pitch.

Polyaminophosphoric Acid-Modified Ion-Imprinted Chitosan Aerogel with Enhanced Antimicrobial Activity for Selective La(III) Recovery and Oil/Water Separation.

In this study, polyaminophosphoric acid (PA)-functionalized ion-imprinted chitosan (CS) aerogel was fabricated for the first time, exhibiting good antibacterial property for selective La(III) recovery and oil/water separation. The as-prepared PA-CS-IIA-2 shows a remarkable adsorption capacity of 114.6 mg/g toward La(III) and high selectivity in the competitive adsorption systems, which is attributed to its abundant imprinting sites and surface functional groups.

Pore structure regulation of hierarchical porous carbon derived from coal tar pitch via pre-oxidation strategy for high-performance supercapacitor.

Carbon materials with rational pore structure have attracted tremendous attention in high-performance supercapacitor applications. However, designing and constructing such carbon materials with excellent performances via a simple and low-cost route is still a challenge. Herein, the nitrogen self-doped oxygen-rich hierarchical porous carbons (OTS-PC) derived from coal tar pitch are constructed via a facile strategy of air pre-oxidation-activation.

Effects of Ion Characteristics on the Leaching of Weathered Crust Elution-Deposited Rare Earth Ore.

To reveal the ion-exchange mechanism in the leaching process of weathered crust elution-deposited rare earth ores with different leaching agents, the effects of a variety of cations and anions at different concentrations on the leaching process were investigated, including Al, Fe, Ca, Mg, Na, K, and Cl, , and . Meanwhile, the relationships between different concentrations of cations and anions and leaching efficiency were investigated, as was the relationship between different concentrations of cations and anions and zeta potential. The effect of different ions on the swelling of clay minerals during leaching process was also investigated.

Simultaneous removal of cationic and anionic dyes from aqueous solution by double functional groups modified bagasse.

Double functional groups modified bagasse (DFMBs), a series of new zwitterionic groups of carboxyl and amine modified adsorbents, were prepared through grafting tetraethylenepentamine (TEPA) onto the pyromellitic dianhydride (PMDA) modified bagasse using the DCC/DMAP method. DFMBs' ability to simultaneously remove basic magenta (BM, cationic dye) and Congo red (CR, anionic dye) from aqueous solution in single and binary dye systems was investigated. FTIR spectra and Zeta potential analysis results showed that PMDA and TEPA were successfully grafted onto the surface of bagasse, and the ratio of the amount of carboxyl groups and amine groups was controlled by the addition of a dosage of TEPA.

Selective removal of phosphate from aqueous solution by MIL-101(Fe)/bagasse composite prepared through bagasse size control.

MIL-101(Fe)/sugarcane bagasse (SCB) with high adsorption capacity and selectivity toward phosphate was prepared through in-situ synthesis method. Effects of bagasse size on the morphology and performances of the composites were investigated, and adsorption behavior and mechanism of phosphate on the composite prepared at the optimum bagasse size were studied. Results showed that composite prepared with bagasse size of 200-300 mesh (MIL-101(Fe)/SCB) showed much higher adsorption capacity than SCB, blank MIL-101(Fe) and the composites prepared with the other bagasse size, which was due to the more positively charged surface and the more exposed adsorption active sites including FeOH and exchangeable Cl.

Effects of surface modification on heavy metal adsorption performance and stability of peanut shell and its extracts of cellulose, lignin, and hemicellulose.

Effects of surface modification by carboxyl group on Pb adsorption performances and stability of peanut shell and its extracts (cellulose, lignin, and hemicellulose) were investigated. Stability of the biosorbents was measured by determining organic compound release amount (TOC). Results showed that adsorption capacity of peanut shell and the extract was poor and stability of them was not good enough.

Novel combined method of biosorption and chemical precipitation for recovery of Pb from wastewater.

A novel combined biosorption-precipitation process has been designed and applied to recycle Pb from low concentration lead containing wastewater. Pb was firstly removed selectively from wastewater by pyromellitic dianhydride (PMDA) modified sugarcane bagasse (SB) fixed-bed column, and then, it was desorbed into the concentrated eluate and recycled by adding chemical precipitant. Adsorption performance of the column and optimum desorption and precipitation condition for Pb were investigated in detail.

A two-step leaching method designed based on chemical fraction distribution of the heavy metals for selective leaching of Cd, Zn, Cu, and Pb from metallurgical sludge.

For selective leaching and highly effective recovery of heavy metals from a metallurgical sludge, a two-step leaching method was designed based on the distribution analysis of the chemical fractions of the loaded heavy metal. Hydrochloric acid (HCl) was used as a leaching agent in the first step to leach the relatively labile heavy metals and then ethylenediamine tetraacetic acid (EDTA) was applied to leach the residual metals according to their different fractional distribution. Using the two-step leaching method, 82.

Selective adsorption and recycle of Cu from aqueous solution by modified sugarcane bagasse under dynamic condition.

Tetraethylenepentamine modified sugarcane bagasse was prepared and applied to test its feasibility in removing and recovering Cu from wastewater under dynamic condition. Results showed that the Cu could be selectively absorbed from wastewater by the modified SCB fixed bed column. To understand the adsorption mechanism, Cd had been selected as the model interfering ion to investigate how co-ions influence the adsorption of Cu on the sorbent.

Simultaneous removal of cationic and anionic dyes by the mixed sorbent of magnetic and non-magnetic modified sugarcane bagasse.

Magnetic carboxyl groups modified (MMS) and non-magnetic amine groups modified (AMS) sugarcane bagasse were prepared and mixed to remove cationic and anionic dye simultaneously from aqueous solution. For comparison, the adsorption performances of MMS, AMS and the mixed sorbent for basic magenta (cationic dye) and congo red (anionic dye) were investigated in the binary system. Zeta potential analysis showed that MMS was negatively charged and AMS was positively charged in the investigated pH range.

[Separation and purification of total flavonids of Astragalus membranaceus with ethanol/phosphate aqueous two-phase system].

Objective: To study separation and purification of flavonids with ethanol/phosphate aqueous two-phase system.

Method: The diversity of phase separation ability and the distribution of target products in various systems were taken as indicators to analyze aqueous two-phase extraction systems and phase diagrams formed by ethanol and some common salts, screen out EtOH/ K2HPO4 system as the optimla system for extracting total flavonids, and study the impact of proportion of components in EtOH/K2 HPO4 system on the partition coefficient and phase ratio of flavonids.

Result And Conclusion: The EtOH/K2 HPO4 system with omegaEtOH 36.

A simple method to prepare magnetic modified beer yeast and its application for cationic dye adsorption.

The purpose of this research is to use a simple method to prepare magnetic modified biomass with good adsorption performances for cationic ions. The magnetic modified biomass was prepared by two steps: (1) preparation of pyromellitic dianhydride (PMDA) modified biomass in N, N-dimethylacetamide solution and (2) preparation of magnetic PMDA modified biomass by a situ co-precipitation method under the assistance of ultrasound irradiation in ammonia water. The adsorption potential of the as-prepared magnetic modified biomass was analyzed by using cationic dyes: methylene blue and basic magenta as model dyes.

A situ co-precipitation method to prepare magnetic PMDA modified sugarcane bagasse and its application for competitive adsorption of methylene blue and basic magenta.

Magnetic pyromellitic dianhydride (PMDA) modified sugarcane bagasse (SCB) was prepared by a situ co-precipitation method. Results showed that the magnetic modified SCB could be recycled easily by an applied magnetic field. Adsorption capacities of the magnetic sorbent for cationic dyes: methylene blue and basic magenta were 315.

Desorption behavior of methylene blue on pyromellitic dianhydride modified biosorbent by a novel eluent: acid TiO2 hydrosol.

In this study, waste beer yeast powder was modified by pyromellitic dianhydride to improve its adsorption capacities for cationic dye: methylene blue (MB). According to the Langmuir equation, the maximum uptake capacities (q(m)) of the modified biomass for MB was 830.8 mg g(-1), which was about five times than that obtained on the unmodified biomass.

Polymer modified biomass of baker's yeast for enhancement adsorption of methylene blue, rhodamine B and basic magenta.

In this study, poly (methacrylic acid) modified biomass was prepared to improve the adsorption capacities for three dyes: methylene blue (MB), rhodamine B (RB) and basic magenta (BM). FTIR and potentiometric titration demonstrated that a large number of carboxyl groups were introduced on the biomass surface, and the concentration of the functional group was calculated to be 1.4 mmol g(-1) by using the first and second derivative method.

Poly(amic acid)-modified biomass of baker's yeast for enhancement adsorption of methylene blue and basic magenta.

In this study, poly(amic acid)-modified biomass was prepared to improve the adsorption capacities for two cationic dyes, methylene blue and basic magenta. X-ray photoelectron spectroscopy and potentiometric titration demonstrated that a large number of imide, amine, and carboxyl groups were introduced on the biomass surface, and the concentrations of these functional groups were calculated to be 0.27, 1.

[Separation and purification of flavonoids from Smilax glabra by macroporous adsorption resin].

Objective: To investigate the process of separating and purifying flavonoids from Smilax glabra.

Method: With the yield of flavonoids as index, the optimum process of separating and purifying flavonoids from S. glabra Roxb was screened by static and dynamic adsorption tests.