The Performance of a Time-Varying Filter Time Under Stable Conditions over Mountainous Terrain.

Eddy-covariance data from five stations in the Inn Valley, Austria, are analyzed for stable conditions to determine the gap scale that separates turbulent from large-scale, non-turbulent motions. The gap scale is identified from (co)spectra calculated from different variables using both Fourier analysis and multi-resolution flux decomposition. A correlation is found between the gap scale and the mean wind speed and stability parameter / that is used to determine a time-varying filter time, whose performance in separating turbulent and non-turbulent motions is compared to the performance of constant filter times between 0.

Influence of grid resolution of large-eddy simulations on foehn-cold pool interaction.

Numerical simulations are performed to assess the influence of horizontal and vertical model resolution on the turbulent erosion of a cold-air pool (CAP) by foehn winds in an Alpine valley near Innsbruck, Austria. Strong wind shear in the transition zone from the CAP to the overlying foehn generates turbulence by shear-flow instability and contributes to the CAP erosion. The sensitivity of this process to grid resolution in the "grey zone" of turbulence is studied with the Weather Research and Forecasting model in large-eddy simulation (LES) mode with a horizontal grid spacing of 200, 40, and 13.

Cold-Air Pool Processes in the Inn Valley During Föhn: A Comparison of Four Cases During the PIANO Campaign.

Unlabelled: We present a comprehensive analysis of four south föhn events observed during the Penetration and Interruption of Alpine Foehn (PIANO) field campaign in the Inn Valley, Austria, in the vicinity of Innsbruck. The goal is to detect and quantify processes of cold-air pool (CAP) erosion by föhn as well as processes of föhn breakdown. Despite differences in föhn breakthrough and strength, the four cases exhibit similarities in CAP evolution: initially, the CAP experienced strongest warming in the centre of Innsbruck, where the föhn jet from the Wipp Valley interacted with the CAP in the Inn Valley.

Large-eddy simulation of foehn-cold pool interactions in the Inn Valley during PIANO IOP 2.

Processes of cold-air pool (CAP) erosion in an Alpine valley during south foehn are investigated based on a real-case large-eddy simulation (LES). The event occurred during the second Intensive Observation Period (IOP 2) of the PIANO field experiment in the Inn Valley, Austria, near the city of Innsbruck. The goal is to clarify the role of advective versus turbulent heating, the latter often being misrepresented in mesoscale models.

How cosmetic tightening products modulate the biomechanics and morphology of human skin.

The active and passive mechanical behavior of a cosmetic tightening product for skin anti-aging is investigated based on a wide range of in vivo and in vitro measurements. The experimental data are used to inform a numerical model of the attained cosmetic effect, which is then implemented in a commercial finite-element framework and used to analyze the mechanisms that regulate the biomechanical interaction between the native tissue and the tightening film. Such a film reduces wrinkles and enhances skin consistency by increasing its stiffness by 48-107% and reducing inelastic, non-recoverable deformations (-47%).

Foehn-cold pool interactions in the Inn Valley during PIANO IOP2.

A case-study is presented of a south foehn emanating from the Wipp Valley, Austria, which encountered a cold-air pool (CAP) in the Inn Valley near the city of Innsbruck. The analysis is based on data collected during the second Intensive Observation Period of the Penetration and Interruption of Alpine Foehn (PIANO) field experiment. Foehn was initiated on 3 November 2017 by an eastward moving trough and terminated in the afternoon of 5 November 2017 by a cold front passage.

Human chemical signature: Investigation on the influence of human presence and selected activities on concentrations of airborne constituents.

There is growing evidence that the very presence of human beings in an enclosed environment can impact air quality by affecting the concentrations of certain airborne volatile organic compounds (VOC). This influence increases considerably when humans perform different activities, such as using toiletries, or simply eating and drinking. To understand the influence of these parameters on the concentrations of selected airborne constituents, a study was performed under simulated residential conditions in an environmentally-controlled exposure room.

Scaling, Anisotropy, and Complexity in Near-Surface Atmospheric Turbulence.

The development of a unified similarity scaling has so far failed over complex surfaces, as scaling studies show large deviations from the empirical formulations developed over flat and horizontally homogeneous terrain as well as large deviations between the different complex terrain data sets. However, a recent study of turbulence anisotropy for flat and horizontally homogeneous terrain has shown that separating the data according to the limiting states of anisotropy (isotropic, two-component axisymmetric and one-component turbulence) improves near-surface scaling. In this paper we explore whether this finding can be extended to turbulence over inclined and horizontally heterogeneous surfaces by examining near-surface scaling for 12 different data sets obtained over terrain ranging from flat to mountainous.

Scalar-Flux Similarity in the Layer Near the Surface Over Mountainous Terrain.

The scaled standard deviations of temperature and humidity are investigated in complex terrain. The study area is a steep Alpine valley, with six measurement sites of different slope, orientation and roughness (i-Box experimental site, Inn Valley, Austria). Examined here are several assumptions forming the basis of Monin-Obukhov similarity theory (MOST), including constant turbulence fluxes with height and the degree of self-correlation between the involved turbulence variables.

Development and validation of a method for quantification of two tobacco-specific nitrosamines in indoor air.

A sensitive and accurate method for the quantification of 1'-Demethyl-1'-nitrosonicotine (NNN) and 4-(methylnitrosamino)-1-(3-Pyridyl)-1-butanone (NNK) in indoor air was developed and validated. To this aim, a novel approach for the collection of two tobacco-specific nitrosamines, using silica sorbent cartridges followed by simplified sample preparation and isotope dilution liquid chromatography/electrospray ionization tandem mass spectrometry, was applied. This procedure led to a substantial improvement in terms of sensitivity and sample throughput as compared with methods using conventional trapping.

The Impact of Three-Dimensional Effects on the Simulation of Turbulence Kinetic Energy in a Major Alpine Valley.

The correct simulation of the atmospheric boundary layer (ABL) is crucial for reliable weather forecasts in truly complex terrain. However, common assumptions for model parametrizations are only valid for horizontally homogeneous and flat terrain. Here, we evaluate the turbulence parametrization of the numerical weather prediction model COSMO with a horizontal grid spacing of for the Inn Valley, Austria.

Numerical ragweed pollen forecasts using different source maps: a comparison for France.

One of the key input parameters for numerical pollen forecasts is the distribution of pollen sources. Generally, three different methodologies exist to assemble such distribution maps: (1) plant inventories, (2) land use data in combination with annual pollen counts, and (3) ecological modeling. We have used six exemplary maps for all of these methodologies to study their applicability and usefulness in numerical pollen forecasts.

Impact of climate change on voltinism and prospective diapause induction of a global pest insect--Cydia pomonella (L.).

Global warming will lead to earlier beginnings and prolongation of growing seasons in temperate regions and will have pronounced effects on phenology and life-history adaptation in many species. These changes were not easy to simulate for actual phenologies because of the rudimentary temporal (season) and spatial (regional) resolution of climate model projections. We investigate the effect of climate change on the regional incidence of a pest insect with nearly worldwide distribution and very high potential for adaptation to season length and temperature--the Codling Moth, Cydia pomonella.

On the efficiency and correction of vertically oriented blunt bioaerosol samplers in moving air.

The aspiration efficiency of vertical and wind-oriented Air-O-Cell samplers was investigated in a field study using the pollen of hazel, sweet chestnut and birch. Collected pollen numbers were compared to measurements of a Hirst-type Burkard spore trap. The discrepancy between pollen counts is substantial in the case of vertical orientation.

A method to derive vegetation distribution maps for pollen dispersion models using birch as an example.

Detailed knowledge of the spatial distribution of sources is a crucial prerequisite for the application of pollen dispersion models such as, for example, COSMO-ART (COnsortium for Small-scale MOdeling-Aerosols and Reactive Trace gases). However, this input is not available for the allergy-relevant species such as hazel, alder, birch, grass or ragweed. Hence, plant distribution datasets need to be derived from suitable sources.

Determination of hydrogen cyanide in cigarette mainstream smoke by LC/MS/MS.

An LC/MS/MS method is presented for the determination of hydrogen cyanide in cigarette mainstream smoke. Cyanide is derivatized with 2,3'-naphthalenedicarboxaldehyde and taurine to form a benzo[f]isoindole derivative, which is then analyzed by LC/MS/MS. Isotopic KCN (K13C15N) was used as an internal standard.