Redox- and Enzyme-Responsive Macrospheres Gatekept by Polysaccharides for Controlled Release of Agrochemicals.

Stimuli-responsive materials afford researchers an opportunity to synthesize controlled-release carriers with various potential applications, especially for reducing the abuse of chemical reagents in farmland soil. To enhance the efficiency of agrochemical utilization, redox- and enzyme-responsive macrospheres were prepared by self-assembling β-cyclodextrin-modified zeolite and ferrocenecarboxylic acid (FcA)-grafted carboxymethyl cellulose (CMC). Scanning electron microscopy and Brunauer-Emmett-Teller analysis revealed that pores of zeolite were sealed by the surface coupling of FcA-modified CMC via the formation of an inclusion complex.