In the European Union, nitrate vulnerable zone (NVZ) should be designed for the mitigation of nitrate (NO) contamination caused by agricultural practices. Before establishing new NVZ, the sources of NO must be recognized. A geochemical and multiple stable isotopes approach (hydrogen, oxygen, nitrogen, sulfur and boron) and statistical tools were applied to define the geochemical characteristics of groundwater (60 samples), calculate the local NO threshold and assess potential sources of NO contamination in two study areas (hereafter Northern and Southern), located in a Mediterranean environment (Sardinia, Italy).
View Article and Find Full Text PDFThis article contains analytical data on chemical composition of waters and solid samples (mining wastes and biominerals) collected in an abandoned mining area, and they are related with the research article "Geochemistry of rare earth elements in water and solid materials at abandoned mines in SW Sardinia (Italy)" (Medas et al., 2013). Specifically, we present physicochemical data (temperature, electrical conductivity, pH, and redox potential), major components and the main contaminants (Zn, Mn, Cd, Ni, Cu, Pb) detected in stream waters and drainages from mine wastes.
View Article and Find Full Text PDFSurface waters, cold and hot springs were collected in different catchments along the Marsyangdi basin, in the Himalayan Range of West-Central Nepal, during the post-monsoon season in 2017 and analyzed for major ions and trace elements, with the aim of assessing the sources of dissolved species and to contribute in watershed planning. The major element data indicate that surface waters coming from the Tethyan Himalayan Sequence (THS) range from the Ca-Mg-HCO to the Ca-Mg-HCO-SO water-types and reflect a two-component mixing of waters from carbonate- and sulfate-bearing sources. The latter component is attributable to sulfide oxidation with minor silicate weathering.
View Article and Find Full Text PDFThis article contains analytical data on Rare Earth Elements (REE) concentration in waters and solid samples (mining wastes and biominerals) collected in an abandoned mining site characterized by near-neutral conditions, and they are related with the research article "Geochemistry of rare earth elements in water and solid materials at abandoned mines in SW Sardinia (Italy)" (Medas et al., 2013). REE can show specific signatures due to fractionation processes, giving an insight to the understanding of the natural processes ruling the water-rock interactions and the geo-bio-interactions.
View Article and Find Full Text PDFChemical speciation [Sb(V) and Sb(III)] affects the mobility, bioavailability and toxicity of antimony. In oxygenated environments Sb(V) dominates whereas thermodynamically unstable Sb(III) may occur. In this study, a simple method for the determination of Sb(III) in non acidic, oxygenated water contaminated with antimony is proposed.
View Article and Find Full Text PDFThis study was aimed to implement the understanding of the Sb behavior in near-surface environments, as a contribution to address appropriate mitigation actions at contaminated sites. For this purpose, geochemical data of soil (8 sites), water (29 sites), and plant (12 sites) samples were collected. The study area is located at Su Suergiu and surroundings in Sardinia (Italy), an abandoned mine area heavily contaminated with Sb, with relevant impact on water bodies that supply water for agriculture and domestic uses.
View Article and Find Full Text PDFUranium mining and processing at Lagoa Real (Bahia, Brazil) started in 2000. Hydrogeochemical monitoring carried out from 1999 to 2001 revealed generally good quality of the water resources outside and inside the mineralized area. No chemical contamination in waters for domestic uses was observed.
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