ACS Appl Mater Interfaces
February 2024
The development of a Co-free and Ni-free electrocatalyst for carbon dioxide electrolysis would be a turning point for the large-scale commercialization of solid-oxide electrolysis cells (CO-SOECs). Indeed, the demand for cobalt and nickel is expected to become critical by 2050 due to automotive electrification. Currently, the reference materials for CO-SOEC electrodes are perovskite oxides containing Mn or Co (anodes) and Ni-YSZ cermets (cathodes).
View Article and Find Full Text PDFAiming at the energy efficient use and valorization of carbon dioxide in the framework of decarbonization studies and hydrogen research, a novel dielectric barrier discharge (DBD) reactor has been designed, constructed and developed. This test rig with water cooled electrodes is capable of a plasma power tunable in a wide range from 20W to 2 kW per unit. The reactor was designed to be ready for catalysts and membrane integration aiming at a broad range plasma conditions and processes, including low to moderate high pressures (0.
View Article and Find Full Text PDFNanostructured cobalt oxide powders as electro catalysts for the oxygen evolution reaction (OER) in an alkaline membrane electrolysis cell (AME) were prepared by flame spray synthesis (FS); an AME's anode was then produced by depositing the FS prepared cobalt oxide powders on an AISI-316 sintered metal fiber by the electrophoretic deposition (EPD) method. FS powders and the composite electrode were characterized by SEM, XRD, and XPS analysis. The electrode showed an increase in the OER catalytic activity in a KOH 0.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
July 2021
In this study, a novel nerve guide conduit was developed, based on a three-dimensional (3D) graphene conductive core grown, by chemical vapor deposition (CVD) coupled with a polycaprolactone (PCL) polymer coating. Firstly, the monolithic 3D-graphene foam (3D-GF) was synthesized on Ni foam templates via inductive heating CVD, subsequently, Ni/Graphene samples were dipped successively in PCL and cyclododecane (CDD) solutions prior to the removal of Ni from the 3D-GF/PCL scaffold in FeCl. Our results showed that the electrical conductivity of the polymer composites reached to 25 S.
View Article and Find Full Text PDFMid-IR absorption of single layer graphene (SLG) was simulated and experimentally demonstrated by embedding a SLG grown by chemical vapor deposition (CVD) inside a Fabry-Perot (FP) filter made by alternating quarter wave Si and layers fabricated by radiofrequency sputtering. The absorption from the graphene layer was modeled by using COMSOL Multiphysics in four different configurations, depending on its position inside the filter, an asymmetric FP made of two different dielectric mirrors separated by a cavity. In the first three configurations, graphene was inserted at the center of the optical cavity and inside the top or bottom dielectric mirror forming the FP.
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